Development of new alumina-modified sorbents for CO2 sorption and regeneration at temperatures below 200 °C

作者: Soo Chool Lee , Yong Mok Kwon , Chun Yong Ryu , Ho Jin Chae , Dhanusuraman Ragupathy

DOI: 10.1016/J.FUEL.2010.11.006

关键词:

摘要: Abstract A new regenerable alumina-modified sorbent was developed for CO 2 capture at temperatures below 200 °C. The capacity of a potassium-based containing Al O 3 (KAlI) decreased during multiple sorption (60 °C) and regeneration (200 °C) tests due to the formation KAl(CO )(OH) phase, which could be converted into original K phase above 300 °C. However, (Re-KAl(I)) maintained its even temperature 130 °C. In particular, Re-KAl(I)60 prepared by impregnation with 60 wt.% about 128 mg /g sorbent. This excellent property were characteristics Re-KAl(I) producing only KHCO sorption, unlike KAlI30 formed phases 60 °C. result explained through structural effect support in presence .

参考文章(37)
Soo Chool Lee, B.Yun Choi, Soo Jae Lee, Suk Yong Jung, Chong Kul Ryu, Jae Chang Kim, CO2 Absorption and Regeneration using Na and K Based Sorbents Carbon Dioxide Utilization for Global Sustainability, Proceedings of 7ththe International Conference on Carbon Dioxide Utilization. ,vol. 153, pp. 527- 530 ,(2004) , 10.1016/S0167-2991(04)80307-0
Zou Yong, Vera G. Mata, Alírio E. Rodrigues, Adsorption of Carbon Dioxide on Chemically Modified High Surface Area Carbon-Based Adsorbents at High Temperature Adsorption-journal of The International Adsorption Society. ,vol. 7, pp. 41- 50 ,(2001) , 10.1023/A:1011220900415
AG Okunev, VE Sharonov, AV Gubar", IG Danilova, EA Paukshtis, EM Moroz, TA Kriger, VV Malakhov, Yu I Aristov, Sorption of carbon dioxide by the composite sorbent "potassium carbonate in porous matrix" Russian Chemical Bulletin. ,vol. 52, pp. 359- 363 ,(2003) , 10.1023/A:1023450614383
Chang-Keun Yi, Sung-Ho Jo, Yongwon Seo, Joong-Beom Lee, Chong-Kul Ryu, Continuous operation of the potassium-based dry sorbent CO2 capture process with two fluidized-bed reactors International Journal of Greenhouse Gas Control. ,vol. 1, pp. 31- 36 ,(2007) , 10.1016/S1750-5836(07)00014-X
Edward B. Rinker, Sami S. Ashour, Orville C. Sandall, Absorption of Carbon Dioxide into Aqueous Blends of Diethanolamine and Methyldiethanolamine Chemical Engineering Science. ,vol. 50, pp. 1071- 1079 ,(1995) , 10.1021/IE990850R
Zou Yong, Mata, Alírio E. Rodrigues, Adsorption of Carbon Dioxide onto Hydrotalcite-like Compounds (HTlcs) at High Temperatures Industrial & Engineering Chemistry Research. ,vol. 40, pp. 204- 209 ,(2001) , 10.1021/IE000238W
Soo Chool Lee, Ho Jin Chae, Soo Jae Lee, Bo Yun Choi, Chang Keun Yi, Joong Beom Lee, Chong Kul Ryu, Jae Chang Kim, Development of regenerable MgO-based sorbent promoted with K2CO3 for CO2 capture at low temperatures. Environmental Science & Technology. ,vol. 42, pp. 2736- 2741 ,(2008) , 10.1021/ES702693C
Z YONG, V MATA, A RODRIGUES, Adsorption of carbon dioxide at high temperature—a review Separation and Purification Technology. ,vol. 26, pp. 195- 205 ,(2002) , 10.1016/S1383-5866(01)00165-4
Y Takamura, Evaluation of dual-bed pressure swing adsorption for CO2 recovery from boiler exhaust gas Separation and Purification Technology. ,vol. 24, pp. 519- 528 ,(2001) , 10.1016/S1383-5866(01)00151-4
Shinichi Hirano, Naoya Shigemoto, Shinichi Yamada, Hiromu Hayashi, Cyclic Fixed-Bed Operations over K2CO3-on-Carbon for the Recovery of Carbon Dioxide under Moist Conditions Bulletin of the Chemical Society of Japan. ,vol. 68, pp. 1030- 1035 ,(1995) , 10.1246/BCSJ.68.1030