EXPANDED PORPHYRINS. RECEPTORS FOR CATIONIC, ANIONIC, AND NEUTRAL SUBSTRATES
作者： Jonathan L. Sessler , Anthony K. Burrell , Hiroyuki Furuta , Gregory W. Hemmi , Brent L. Iverson
DOI: 10.1007/978-94-015-8380-0_21
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摘要: The syntheses and applications of a variety new previously reported expanded por phyrins are reviewed the general cation anion binding properties these systems discussed. Emphasis is devoted to texaphyrins, anthraphyrins, alaskaphyrins, USAphyrins, sapphyrins, pentaphyrins, rubyrins, rosarins, turcasarins. use pentaphyrins alaskaphyrins as uranyl (UO/+) complexing agents presented advantages using texaphyrins bind coordinatively trivalent lanthanide cations. other porphyrins, notably octaaza for non ionic recognition alcohol-derived neutral substrates also summarized extensive coordination chemistry associated with Special emphasis, in latter context, given unique phosphate chelation novel, non intercalative DNA capabilities sapphyrin.
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