Structural study of antimony borate glass system doped with transition metal ions using infrared and Raman spectroscopy

摘要: A series of Antimony Borate glass samples were investigated to determine the structural feature. The from xSb2O3:(1-x)B2O3 with composition 20≤x≤60 mol% and 0.6 Sb2O3:0.4B2O3:y y is 0.01 Nb2O5, CuO, ZnO system have been prepared using melt-quenching technique. properties Sb2O3 host introduction dopents onto sample has Infrared RAMAN Spectroscopy. result IR Raman Spectroscopy revealed that network structure studied glasses mainly based on BO3 BO4 units placed in different groups, being dominant. spectra obtained shows conversion upon commonly known as boron anomaly effect. can be modified presence activator ions. significant behavior Spectra indicates boroxol groups consisting pure mixed BO3-BO4 units. This study vibrational spectroscopy (Infrared Raman) provide useful method, inter-complementary information about antimony borate glasses.