Achieving non-contact optical thermometer via inherently Eu2+/Eu3+-activated SrAl2Si2O8 phosphors prepared in air

作者: Junpeng Xue , Mingjun Song , Hyeon Mi Noh , Sung Heum Park , Byung Chun Choi

DOI: 10.1016/J.JALLCOM.2020.155858

关键词:

摘要: Abstract Eu2+/Eu3+-activated SrAl2Si2O8 phosphors, which presented blue emission originating from 4f65d → 4f7 transition of Eu2+ ions and red arising 5D0 7FJ Eu3+ ions, were synthesized by the traditional solid-state reaction in air. The photoluminescence intensities increased with increasing dopant content reached their maximum value when doping concentration was 3 mol%. Moreover, based on diverse thermal quenching behaviors thermometric performance SrAl2Si2O8: Eu2+/Eu3+ phosphors investigated fluorescence intensity ratio technology. absolute sensitivity relative sensitivities 0.056 K-1 0.30% K−1, respectively, at temperature 583 K. Also, effects different excitation wavelength studied detail. On other hand, through analyzing various responses decay time to temperature, performances also discussed range 298–573 K. up 0.22% K−1 573 K. These results suggested that had potential field non-contact optical thermometry.

参考文章(56)
W. H. Fonger, C. W. Struck, Eu+35D Resonance Quenching to the Charge‐Transfer States in Y2O2S, La2O2S, and LaOCl The Journal of Chemical Physics. ,vol. 52, pp. 6364- 6372 ,(1970) , 10.1063/1.1672952
Bitao Liu, Yuhua Wang, Jun Zhou, Feng Zhang, Zhaofeng Wang, The reduction of Eu3+ to Eu2+ in BaMgAl10O17:Eu and the photoluminescence properties of BaMgAl10O17:Eu2+ phosphor Journal of Applied Physics. ,vol. 106, pp. 053102- ,(2009) , 10.1063/1.3211301
Bin Dong, Baosheng Cao, Yangyang He, Zhuang Liu, Zhipeng Li, Zhiqing Feng, Temperature Sensing and In Vivo Imaging by Molybdenum Sensitized Visible Upconversion Luminescence of Rare-Earth Oxides Advanced Materials. ,vol. 24, pp. 1987- 1993 ,(2012) , 10.1002/ADMA.201200431
V. Lojpur, M. Nikolic, L. Mancic, O. Milosevic, M.D. Dramicanin, Y2O3:Yb,Tm and Y2O3:Yb,Ho powders for low-temperature thermometry based on up-conversion fluorescence Ceramics International. ,vol. 39, pp. 1129- 1134 ,(2013) , 10.1016/J.CERAMINT.2012.07.036
Su Zhang, Hongbin Liang, Yufeng Liu, Temperature-sensitive fluorescence of NaRETiO4:Pr3+ (RE = Y, Gd) based on the intervalence charge transfer between Pr3+ and Ti4+ Journal of Applied Physics. ,vol. 115, pp. 073511- ,(2014) , 10.1063/1.4865960
Santosh K. Gupta, M. Mohapatra, S. V. Godbole, V. Natarajan, On the unusual photoluminescence of Eu3+ in α-Zn2P2O7: a time resolved emission spectrometric and Judd–Ofelt study RSC Advances. ,vol. 3, pp. 20046- 20053 ,(2013) , 10.1039/C3RA43027H
Qinghua Zeng, Zhiwu Pei, Shubing Wang, Qiang Su, Shaozhe Lu, Luminescent properties of divalent samarium-doped strontium hexaborate Chemistry of Materials. ,vol. 11, pp. 605- 611 ,(1999) , 10.1021/CM980479I
Jian Chen, Yangai Liu, Haikun Liu, Hao Ding, Minghao Fang, Zhaohui Huang, None, Tunable SrAl2Si2O8: Eu phosphor prepared in air via valence state-controlled means Optical Materials. ,vol. 42, pp. 80- 86 ,(2015) , 10.1016/J.OPTMAT.2014.12.023
Lorenz H. Fischer, Gregory S. Harms, Otto S. Wolfbeis, Upconverting Nanoparticles for Nanoscale Thermometry Angewandte Chemie. ,vol. 50, pp. 4546- 4551 ,(2011) , 10.1002/ANIE.201006835
Mingying Peng, Zhiwu Pei, Guangyan Hong, Qiang Su, The reduction of Eu3+ to Eu2+ in BaMgSiO4∶Eu prepared in air and the luminescence of BaMgSiO4∶Eu2+ phosphor Journal of Materials Chemistry. ,vol. 13, pp. 1202- 1205 ,(2003) , 10.1039/B211624C