3-Aminopropyl-triethoxysilane-functionalized rice husk and rice husk ash reinforced polyamide 6/graphene oxide sustainable nanocomposites

作者: Ahmad Allahbakhsh , Fereidoun Noei Khodabadi , Fatemeh Sadat Hosseini , Amir Hossein Haghighi

DOI: 10.1016/J.EURPOLYMJ.2017.07.031

关键词:

摘要: Abstract Rice husk and rice ash are two well-known sustainable materials for wastewater purification applications. In this work, functionalized-rice -rice reinforced polyamide 6/graphene oxide nanocomposites fabricated using the solution casting method. 3-Aminopropyl-triethoxysilane is used as functionalizing agent surface modification of particles. Siloxane bonding between silanol groups silica containing particles can result in introduction amino on particles, which react with either terminal carboxyl or amide 6. Functionalized-rice ash, contains a large amount nano silica, forms distributed nano-sized aggregates structure Moreover, simultaneous presence graphene an organic/inorganic nano-system, matrix results clear enhancement structural mechanical characteristics final nanocomposites. This possible strong interactions polymeric nano-system. The influences nano-system melting process, morphology dynamic-mechanical properties investigated details. impacts loading thermal stability studied. Considering presented here adsorbent nanoparticles, ash/graphene oxide/polyamide 6 nanocomposite perfect candidate fabricating nanofibers, applicable

参考文章(58)
Reza Arjmandi, Azman Hassan, Khaliq Majeed, Zainoha Zakaria, Rice Husk Filled Polymer Composites International Journal of Polymer Science. ,vol. 2015, pp. 798- 829 ,(2015) , 10.1155/2015/501471
Hans E. Miltner, Guy Van Assche, András Pozsgay, Béla Pukánszky, Bruno Van Mele, Restricted chain segment mobility in poly(amide) 6/clay nanocomposites evidenced by quasi-isothermal crystallization Polymer. ,vol. 47, pp. 826- 835 ,(2006) , 10.1016/J.POLYMER.2005.12.014
Takashi Itoh, Hideki Miyaji, Kenjiro Asai, Thermal Properties of α- and γ-Forms of Nylon 6 Japanese Journal of Applied Physics. ,vol. 14, pp. 206- 215 ,(1975) , 10.1143/JJAP.14.206
Yan Zhang, Yanwu Zhu, Gui Lin, Rodney S. Ruoff, Naiping Hu, Dale W. Schaefer, James E. Mark, What factors control the mechanical properties of poly (dimethylsiloxane) reinforced with nanosheets of 3-aminopropyltriethoxysilane modified graphene oxide? Polymer. ,vol. 54, pp. 3605- 3611 ,(2013) , 10.1016/J.POLYMER.2013.04.057
John A. Howarter, Jeffrey P. Youngblood, Surface Modification of Polymers with 3-Aminopropyltriethoxysilane as a General Pretreatment for Controlled Wettability Macromolecules. ,vol. 40, pp. 1128- 1132 ,(2007) , 10.1021/MA062028M
Haihui Liu, Lichen Hou, Weiwei Peng, Qiang Zhang, Xingxiang Zhang, Fabrication and characterization of polyamide 6-functionalized graphene nanocomposite fiber Journal of Materials Science. ,vol. 47, pp. 8052- 8060 ,(2012) , 10.1007/S10853-012-6695-5
Peng Cui, Junghyun Lee, Eunhee Hwang, Hyoyoung Lee, One-pot reduction of graphene oxide at subzero temperatures Chemical Communications. ,vol. 47, pp. 12370- 12372 ,(2011) , 10.1039/C1CC15569E
Shaobo Xie, Shimin Zhang, Fosong Wang, Mingshu Yang, Roland Séguéla, Jean-Marc Lefebvre, Preparation, structure and thermomechanical properties of nylon-6 nanocomposites with lamella-type and fiber-type sepiolite Composites Science and Technology. ,vol. 67, pp. 2334- 2341 ,(2007) , 10.1016/J.COMPSCITECH.2007.01.012
A. Bahrami, M.I. Pech-Canul, C.A. Gutierrez, N. Soltani, Effect of rice-husk ash on properties of laminated and functionally graded Al/SiC composites by one-step pressureless infiltration Journal of Alloys and Compounds. ,vol. 644, pp. 256- 266 ,(2015) , 10.1016/J.JALLCOM.2015.04.194