Device and method for aryl-alkyl coupling using decarboxylation
作者： Mukund Karanjikar , Sai Bhavaraju , Patrick Mcguire , James Mosby
DOI:
关键词:
摘要: A method for alkylating aromatic compounds is described using an electrochemical decarboxylation process. This process produces aryl-alkyl that have properties useful in Group V lubricants (and other products) from abundant and economical carboxylic acids. The presented here also advantageous as it conducted at moderate temperatures conditions, without the need of a catalyst. has only H2 CO2 its by-products, opposed to halide by-products.
lens.org 参考文章(7)
Hans-Jürgen Schäfer, Recent contributions of kolbe electrolysis to organic synthesis Electrochemistry IV. ,vol. 152, pp. 91- 151 ,(1990) , 10.1007/BFB0034365
Sai Bhavaraju, Mukund Karanjikar, Electrochemical synthesis of aryl-alkyl surfactant precursor ,(2011)
Rainer Busch, Biofuel composition and manufacturing process ,(2008)
Sven Ivar Hommeltoft, Bi-Zeng Zhan, Conversion of fatty acids to base oils and transportation fuels ,(2012)
Sai Bhavaraju, David Joel Hunt, Ashok V. Joshi, Pallavi Chitta, Mukund Karanjikar, Decarboxylation cell for production of coupled radical products ,(2010)
Sai Bhavaraju, Ashok V. Joshi, Justin Pendleton, Production of alkali bicarbonate and alkali hydroxide from alkali carbonate in an electrolytic cell ,(2011)
George Edwin Harrison, Process for the commercial production of polyhydroxy alcohols and glycols ,(1996)