Crystal structure of trichlorooxo-17-bis[(diphenylphosphoryl)methyl]- 4(24),6(10),12(16),18(22)-tetramethylenedioxy-2,8,14,20- tetrapentylresorcin[4]areneuranium(V) -dichlorodioxo-17- bis[(diphenylphosphoryl)methyl]-4(24),6(10),12(16),18(22)- tetramethylenedioxy-2,8,14,20-tetrapentylresorcin[4]areneuranium(VI) - hexane (1:3:3), UCl3O(C78H86O10P2) · 3UCl2O2(C78H86O10P2) · 3C6H14

作者: Hani El Moll , David Sémeril , Dominique Matt , Loïc Toupet

DOI: 10.1524/NCRS.2011.0044

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摘要: Ci(65)H(193)CL(4.36)O(23.64)P(4)U(2), triclinic, P (1) over bar (no. 2), a = 15.495(1) angstrom, b 18.855(2) c =30.532(3) alpha 90.717(9)degrees, beta 101.253(7)degrees, gamma 109.575(9)degrees, V 8213.9 angstrom(3), Z 2, R-gt(F)= 0.055, wR(ref)(F-2)= 0.152, T= 110 K.

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