Analytical separation of rhenium by extraction with n-benzylaniline in chloroform from sulphuric acid media

作者: M.M.L. Khosla , S.P. Rao

DOI: 10.1016/S0003-2670(01)95055-X

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摘要: Abstract Analytical separation of rhenium(VII) is achieved by solvent extraction with N-benzylaniline in chloroform from sulphuric acid media. Few cations interfere: common anions such as phosphate, tartrate, citrate, oxalate, fluoride, EDTA and ascorbic do not interfere. A simple method described for the micro amounts rhenium macro molybdenum, tungsten, niobium tantalum. The also separates V, Cr, Se, Te, Os, Ru, Rh, Pd Pt. molar absorptivity thiocyanate complex butyl acetate diisopropyl ether 40280 ± 280 at 430 nm.

参考文章(13)
V. M. Shinde, Shripad M. Khopkar, Liquid-liquid extraction of rhenium(VII) with mesityl oxide Analytical Chemistry. ,vol. 43, pp. 473- 474 ,(1971) , 10.1021/AC60298A032
T. M. Cotton, A. A. Woolf, Determination of Rhenium in Tungsten and Molybdenum Alloys. Analytical Chemistry. ,vol. 36, pp. 248- 249 ,(1964) , 10.1021/AC60207A078
V. Yatirajam, Die extraktive Abtrennung des Rheniums aus salz- und schwefelsauren Lösungen und ihre analytische Anwendung Fresenius Journal of Analytical Chemistry. ,vol. 219, pp. 128- 136 ,(1966) , 10.1007/BF00534730
Max Ziegler, Hartmut Schroeder, Extraktion des Rheniums als Tributylammoniumperrhenat Fresenius Journal of Analytical Chemistry. ,vol. 212, pp. 395- 401 ,(1965) , 10.1007/BF00519383
V. Yatirajam, R. Prosad, Separation of rhenium from molybdenum and vanadium by extraction with amyl alcohol Fresenius Journal of Analytical Chemistry. ,vol. 220, pp. 340- 345 ,(1966) , 10.1007/BF00505095
W. J. Maeck, G. L. Booman, M. E. Kussy, J. E. Rein, Extraction of the Elements as Quaternary (Propyl, Butyl, and Hexyl) Amine Complexes Analytical Chemistry. ,vol. 33, pp. 1775- 1780 ,(1961) , 10.1021/AC60180A045