Retinoide und Carotinoide, V. Synthese von modifizierten Retinalen

作者: Hans Jürgen Bestmann , Peter Ermann , Hartmann Rüppel , Walter Sperling

DOI: 10.1002/JLAC.198619860307

关键词:

摘要: Die Synthesen von 13-Desmethyl-13-ethyl-, 13-Desmethyl-13-propyl-, 13-Desmethyl-, 13-Desmethyl-14-methyl- und 14-Methylretinal werden beschrieben. UV-Spektren verschiedener geometrischer Isomerer der Verbindungen diskutiert. Retinoids and Carotenoids, V. — Synthesis of Modified Retinals The syntheses 13-demethyl-13-ethyl-, 13-demethyl-13-propyl-, 13-demethyl-, 13-demethyl-14-methyl-, 14-methylretinal are described. The UV spectra some geometric isomers these compounds discussed.

参考文章(46)
W. Sperling, Conformations of 11-cis Retinal Springer, Berlin, Heidelberg. pp. 19- 28 ,(1973) , 10.1007/978-3-642-85769-0_3
Hans Jürgen Bestmann, Otto Vostrowsky, Selected topics of the wittig reaction in the synthesis of natural products ChemInform. ,vol. 14, pp. 85- 163 ,(1983) , 10.1007/BFB0018057
Hans Jürgen Bestmann, Peter Ermann, Reaktionen mit Phosphinalkylenen, 44. Eine weitere Synthese von (Z)‐α,β‐ungesättigten Aldehyden Chemische Berichte. ,vol. 116, pp. 3264- 3266 ,(1983) , 10.1002/CBER.19831160922
Rudolf Criegee, Peter Dimroth, Klaus Noll, Renate Simon, Umlagerungen bei Oxydationen mit Bleitetraacetat Chemische Berichte. ,vol. 90, pp. 1070- 1081 ,(1957) , 10.1002/CBER.19570900630
R. GILARDI, I. L. KARLE, J. KARLE, W. SPERLING, Crystal structure of the visual chromophores, 11-cis and all-trans retinal. Nature. ,vol. 232, pp. 187- 189 ,(1971) , 10.1038/232187C0
Pius A. WEHRLI, Beatrice SCHAER, Synthesis of γ-Acetoxytiglicaldehyde from Isoprene Synthesis. ,vol. 1977, pp. 649- 650 ,(1977) , 10.1055/S-1977-24520
James H. Babler, Michael J. Coghlan, Marguerite Feng, Peter Fries, Facile synthesis of 4-acetoxy-2-methyl-2-butenal, a vitamin A precursor, from isoprene chlorohydrin Journal of Organic Chemistry. ,vol. 10, pp. 1716- 1717 ,(1979) , 10.1021/JO01324A030
Rainer Uhl, E. W. Abrahamson, Dynamic processes in visual transduction Chemical Reviews. ,vol. 81, pp. 291- 312 ,(1981) , 10.1021/CR00043A004
H. J. Bestmann, Old and new ylid chemistry Pure and Applied Chemistry. ,vol. 52, pp. 771- 788 ,(1980) , 10.1351/PAC198052040771