Synthesis, characterization, EXAFS investigation and antibacterial activities of new ruthenium(III) complexes containing tetradentate Schiff base
作者： R. Prabhakaran , A. Geetha , M. Thilagavathi , R. Karvembu , Venkata Krishnan
DOI: 10.1016/J.JINORGBIO.2004.09.020
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摘要: A series of new hexa-coordinated ruthenium(III) complexes the type [Ru(X)(2-atmp-ba)(EPh3)] (where H2-2-atmp-ba=N,N'-bis(2-aminothiophenol)benzoylacetone; X=Cl or Br; E=P As) have been prepared by reacting [RuX3(EPh3)3] with tetradentate Schiff base ligand (H2-2-atmp-ba) in 1:1 molar ratio. The characterized elemental analyses, Infra red, electronic, electron paramagnetic resonance spectroscopy and cyclic voltammetry. In order to confirm coordination structure extended X-ray absorption fine (EXAFS) studies carried out. Based on above data, an octahedral has confirmed for complexes. were also screened their antibacterial properties.
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