Competitive Sorption of Copper and Nickel Ions from Aqueous Solution Using Peat

作者: YS Ho , G McKay , None

DOI: 10.1023/A:1008921002014

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摘要: Bicomponent aqueous solutions of copper and nickel ions have been used to investigate the sorption metal onto peat. Peat, a low cost sorbent, has shown high capacity for single component attributed extensive carboxylic acids within its structure. Copper were selected as typical metals in effluents electroplating industries. The effects competitive batch systems studied at various ion concentrations. In this study Butler Ockrent model was modified using coefficient, η. Two models developed based on interaction coefficient first incorporates constant fixed η factor each into Butler-Ockrent equation. second variable equation; varies function sorbent surface coverage. Predicted equilibrium data are found be excellent agreement with experimental values both mole ratios sorption.

参考文章(35)
A. Seidel, G. Reschke, S. Friedrich, D. Gelbin, Equilibrium adsorption of two-component organic solutes from aqueous solutions on activated carbon Adsorption Science & Technology. ,vol. 3, pp. 189- 199 ,(1986) , 10.1177/026361748600300309
Carmen Gabaldón, Paula Marzal, Jose Ferrer, Aurora Seco, Single and competitive adsorption of Cd and Zn onto a granular activated carbon Water Research. ,vol. 30, pp. 3050- 3060 ,(1996) , 10.1016/S0043-1354(96)00165-0
Elias I. Franses, Faisal A. Siddiqui, Dong June Ahn, Chien-Hsiang Chang, Nien-Hwa Linda Wang, Thermodynamically Consistent Equilibrium Adsorption Isotherms for Mixtures of Different-Size Molecules Langmuir. ,vol. 11, pp. 3177- 3183 ,(1995) , 10.1021/LA00008A050
Orhan Talu, Alan L. Myers, Rigorous thermodynamic treatment of gas adsorption AIChE Journal. ,vol. 34, pp. 1887- 1893 ,(1988) , 10.1002/AIC.690341114
C. J. Radke, J. M. Prausnitz, Thermodynamics of multi-solute adsorption from dilute liquid solutions AIChE Journal. ,vol. 18, pp. 761- 768 ,(1972) , 10.1002/AIC.690180417
G. Mckay, Peat for Environmental Applications: A Review Developments in Chemical Engineering and Mineral Processing. ,vol. 4, pp. 127- 155 ,(2008) , 10.1002/APJ.5500040302
D.C. Shallcross, C.C. Herrmann, B.J. McCoy, An improved model for the prediction of multicomponent ion exchange equilibria Chemical Engineering Science. ,vol. 43, pp. 279- 288 ,(1988) , 10.1016/0009-2509(88)85040-1
VI. Experimental researches in electricity.—Sixth series Philosophical Transactions of the Royal Society. ,vol. 124, pp. 55- 76 ,(1834) , 10.1098/RSTL.1834.0007