Performances of Cr 2 O 3 –hydrogen isotopes permeation barriers

作者: Qun Li , Li-Bin Mo , Jie Wang , Kai Yan , Tao Tang

DOI: 10.1016/J.IJHYDENE.2015.03.093

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摘要: Abstract Hydrogen isotopes permeation barriers (HIPB) play an important role in reducing hydrogen and leakage energy thermonuclear fusion energy. In this study, the Cr2O3–HIPB were prepared on 316L stainless steel by RF magnetron sputtering. The performances of investigated, including deuterium-permeation reduction factor (D-PRF), micro-structure nano-hardness. D-PRF 0.5 μm could reach 48 at 700 °C 152 400 °C first test cycle. However, it reduced to 20 89 second (012), (104), (113) (116) diffraction peaks occurred morphologies became loose after high temperature annealing. nano-hardness decreased 31% from 9.1 GPa 6.3 GPa with increasing annealing time 64 h. It was inferred that invasion should be responsible for performance evolution the Cr2O3–HIPB under temperatures. Furthermore, FeCr2O4 phase formed the interfaces as a result element diffusion, which might contribute cracking Cr2O3–HIPB.

参考文章(29)
Rajesh V. Pai, K. Krishnan, Smruti Dash, S.K. Mukerjee, V. Venugopal, Synthesis, characterization and thermal expansion of Cr2−xTixO3+δ Journal of Alloys and Compounds. ,vol. 507, pp. 267- 272 ,(2010) , 10.1016/J.JALLCOM.2010.07.175
Guikai Zhang, Xiaolin Wang, Yifu Xiong, Yan Shi, Jiangfeng Song, Deli Luo, Mechanism for adsorption, dissociation and diffusion of hydrogen in hydrogen permeation barrier of α-Al2O3: A density functional theory study International Journal of Hydrogen Energy. ,vol. 38, pp. 1157- 1165 ,(2013) , 10.1016/J.IJHYDENE.2012.10.108
L. Marchetti, E. Herms, P. Laghoutaris, J. Chêne, Hydrogen embrittlement susceptibility of tempered 9%Cr–1%Mo steel International Journal of Hydrogen Energy. ,vol. 36, pp. 15880- 15887 ,(2011) , 10.1016/J.IJHYDENE.2011.08.096
J. Konys, W. Krauss, N. Holstein, J. Lorenz, S. Wulf, K. Bhanumurthy, Impact of heat treatment on surface chemistry of Al-coated Eurofer for application as anti-corrosion and T-permeation barriers in a flowing Pb–15.7Li environment Fusion Engineering and Design. ,vol. 87, pp. 1483- 1486 ,(2012) , 10.1016/J.FUSENGDES.2012.03.042
Qinghe Yu, Lei Hao, Shuai Li, Di He, Xiaopeng Liu, Lijun Jiang, Shumao Wang, Microstructure and deuterium permeation resistance of the oxide scale prepared by initial oxidation method on vacuum solar receiver Solid State Ionics. ,vol. 231, pp. 5- 10 ,(2013) , 10.1016/J.SSI.2012.11.004
Bojan Zajec, Hydrogen permeation barrier – Recognition of defective barrier film from transient permeation rate International Journal of Hydrogen Energy. ,vol. 36, pp. 7353- 7361 ,(2011) , 10.1016/J.IJHYDENE.2011.03.068
H.G. Yang, Q. Zhan, W.W. Zhao, X.M. Yuan, Y. Hu, Z.B. Han, Study of an iron-aluminide and alumina tritium barrier coating Journal of Nuclear Materials. ,vol. 417, pp. 1237- 1240 ,(2011) , 10.1016/J.JNUCMAT.2011.03.040
Junyou Yang, Hui Chen, Jiansheng Zhang, Shuanglong Feng, Ming Liu, Gen Li, Jiangying Ping, Qiongzhen Liu, Youwei Yan, Preparation of Er2O3 coating on a low activation martensitic steel substrate via the route of sol–gel Surface & Coatings Technology. ,vol. 205, pp. 5497- 5501 ,(2011) , 10.1016/J.SURFCOAT.2011.06.020
Guikai Zhang, Xiaolin Wang, Feilong Yang, Yan Shi, Jiangfeng Song, Xinchun Lai, Energetics and diffusion of hydrogen in hydrogen permeation barrier of α-Al2O3/FeAl with two different interfaces International Journal of Hydrogen Energy. ,vol. 38, pp. 7550- 7560 ,(2013) , 10.1016/J.IJHYDENE.2013.03.136