Integrating Electrocatalytic 5-Hydroxymethylfurfural Oxidation and Hydrogen Production via Co–P-Derived Electrocatalysts

作者: Nan Jiang , Bo You , Raquel Boonstra , Irina M. Terrero Rodriguez , Yujie Sun

DOI: 10.1021/ACSENERGYLETT.6B00214

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摘要: Electrocatalytic biomass valorization with renewable energy input represents a promising way to produce sustainable and nonfossil-based carbon products. Even more desirable is that the oxidative biomass upgrading can be integrated with H2 production in a single electrolyzer. Herein, we report that electrodeposited Co–P can act as competent electrocatalysts for 5-hydroxymethylfurfural (HMF) oxidation to 2, 5-furandicarboxylic acid (FDCA) at the anode and H2 production at the cathode simultaneously in alkaline media …

参考文章(36)
H.B. Goyal, Diptendu Seal, R.C. Saxena, Bio-fuels from thermochemical conversion of renewable resources: A review Renewable & Sustainable Energy Reviews. ,vol. 12, pp. 504- 517 ,(2008) , 10.1016/J.RSER.2006.07.014
Michael G. Walter, Emily L. Warren, James R. McKone, Shannon W. Boettcher, Qixi Mi, Elizabeth A. Santori, Nathan S. Lewis, Solar Water Splitting Cells Chemical Reviews. ,vol. 110, pp. 6446- 6473 ,(2010) , 10.1021/CR1002326
Koteswara Rao Vuyyuru, Peter Strasser, Oxidation of biomass derived 5-hydroxymethylfurfural using heterogeneous and electrochemical catalysis Catalysis Today. ,vol. 195, pp. 144- 154 ,(2012) , 10.1016/J.CATTOD.2012.05.008
Timothy R. Cook, Dilek K. Dogutan, Steven Y. Reece, Yogesh Surendranath, Thomas S. Teets, Daniel G. Nocera, Solar Energy Supply and Storage for the Legacy and Nonlegacy Worlds Chemical Reviews. ,vol. 110, pp. 6474- 6502 ,(2010) , 10.1021/CR100246C
Maria J. Climent, Avelino Corma, Sara Iborra, Converting carbohydrates to bulk chemicals and fine chemicals over heterogeneous catalysts Green Chemistry. ,vol. 13, pp. 520- 540 ,(2011) , 10.1039/C0GC00639D
Avelino Corma, Sara Iborra, Alexandra Velty, Chemical Routes for the Transformation of Biomass into Chemicals Chemical Reviews. ,vol. 107, pp. 2411- 2502 ,(2007) , 10.1021/CR050989D
H. I. Karunadasa, E. Montalvo, Y. Sun, M. Majda, J. R. Long, C. J. Chang, A Molecular MoS2 Edge Site Mimic for Catalytic Hydrogen Generation Science. ,vol. 335, pp. 698- 702 ,(2012) , 10.1126/SCIENCE.1215868
Sara E. Davis, Levi R. Houk, Erin C. Tamargo, Abhaya K. Datye, Robert J. Davis, Oxidation of 5-hydroxymethylfurfural over supported Pt, Pd and Au catalysts Catalysis Today. ,vol. 160, pp. 55- 60 ,(2011) , 10.1016/J.CATTOD.2010.06.004