INTRAMICELLAR QUENCHING OF 2,3-DIMETHYLNAPHTHALENE FLUORESCENCE BY PEROXIDES and HYDROPEROXIDES
作者： M. V. Encinas , E. A. Lissi
DOI: 10.1111/J.1751-1097.1983.TB04469.X
关键词:
摘要: Hydrogen peroxide, t-butyl hydroperoxide, di-t-butyl peroxide and dibenzoyl efficiently quench the fluorescence of 2,3-dimethylnaphthalene incorporated into sodium dodecyl sulfate cetyltrimethylammonium chloride micelles. Potassium persulfate only is effective when probe a cationic micelle. The binding constant peroxides intramiccllar quenching rate constants have been evaluated for all systems considered data are compared to that obtained in homogeneous solution. It concluded that, even processes which not diffusion controlled, process slower
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