7.09 Oxidation of C–H Bond Adjacent to Oxygen of Ethers
作者： Y. Obora , Y. Ishii
DOI: 10.1016/B978-0-08-097742-3.00710-2
关键词:
摘要: A variety of reaction examples and the method for oxidation C–H bonds adjacent to oxygen atom ethers have been illustrated. Ethers are well known be subject autoxidation under influence molecular generate peroxides or their decomposed products. converted into aldehydes, carboxylic acids, ketones, esters by action various oxidants including metallic such as chromium-based reagents, peroxide, ozone, oxygen. Electrochemical is adopted in oxidative functionalization neighboring ethers. The application ether C–C bond formation total synthesis asymmetric has documented.
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