Studies on the reactivity of group 15 Zintl ions with carbodiimides: synthesis and characterization of a heptaphosphaguanidine dianion
作者： Robert S. P. Turbervill , Jose M. Goicoechea
DOI: 10.1039/C1CC12089A
关键词:
摘要: Reaction of the hydrogenheptaphosphide dianion, [HP7]2−, with one equivalent bis(2,6-diisopropylphenyl)carbodiimide yielded exo-functionalized cluster [P7C(NDipp)(NHDipp)]2− (Dipp = 2,6-diisopropylphenyl). This species was characterized by single crystal X-ray diffraction, multielement NMR spectroscopy and electrospray mass-spectrometry. DFT calculations on dianion were also conducted.
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