Single-molecule vibrational spectroscopy and microscopy: CO on Cu(001) and Cu(110)

作者: L. J. Lauhon , W. Ho

DOI: 10.1103/PHYSREVB.60.R8525

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摘要: Single-molecule vibrations of four isotopes CO on Cu(001) and Cu(110) at 8 K have been measured by inelastic electron tunneling spectroscopy with the scanning microscope (STM-IETS). While low energy hindered rotation exhibits strong intensity, C-O stretch approaches present detection limit STM-IETS. By performing vibrational microscopy, spatial distribution intensity is found to be more localized than topographic depression in constant current images.

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