Highly reversible sorption of H2S and CO2 by an environmentally friendly Mg-based MOF

作者: Elí Sánchez-González , Paulo GM Mileo , Mónica Sagastuy-Breña , J Raziel Álvarez , Joseph E Reynolds

DOI: 10.1039/C8TA05400B

关键词:

摘要: Mg-CUK-1, an ecologically friendly material synthesised in water is found to be a high-capacity, highly reversible adsorbent for acidic gases including H2S and CO2. Furthermore, Mg-CUK-1 demonstrated retain long-range crystallinity upon sorption cycling; its performance maintained over multiple cycles, even the presence of high relative humidity (95%). Reversible adsorption by rare among MOFs studied this purpose date. The joint experimental computational studies presented here show that effective solid applications field acid gas capture, application relevant purification many industrial streams.

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