Synthesis and electrochemistry of vanadium(IV) Schiff base complexes
作者： A. H. Kianfar , S. Mohebbi
DOI: 10.1007/BF03245969
关键词:
摘要: The electrochemical properties of vanadyl(IV) derivatives, namely salen Schiff base complexes the type [VO(Salen)] (5-BrSalen, 5-NO2Salen, 5-MeOSalen, salpn (bis(salicylaldehyde)-1,3-propanediamine, 5-BrSalpn, 5-NO2Salpn, 5-MeOSalpn, Me2Salen, Salophen, 5-BrSalophen, and 5-MeOSalophen) were investigated. equatorial ligands affect oxidation potentials via interaction with d-orbitals vanadyl metal ion. cathodic peak potential (Epc) becomes less negative according to sequence MeO- < H- Br- NO2−.
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