Living anionic stereospecific polymerization of 2-vinylpyridine, 1. Initiation of polymerization and stereoregularity of polymers

作者: Alain Soum , Michel Fontanille

DOI: 10.1002/MACP.1980.021810404

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摘要: Initiation of the polymerization 2-vinylpyridine by organomagnesium compounds in hydrocarbon solvents, was obtained without side reactions on pyridine rings. The resulting active centres are unsymmetrical. They stable and stereospecific, leading to living polymers with an isotacticity degree about 0,9.

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