Rotational energy transfer in vibrationally excited acetylene X̃ 1Σg(ν2‘=1,J‘):ΔJ propensities
作者： R. Dopheide , W. Cronrath , H. Zacharias
DOI: 10.1063/1.467295
关键词:
摘要: A complete set of state‐to‐state rotational energy transfer rate constants has been measured for acetylene–acetylene collisions at room temperature under single collision conditions. Initial states (Ji=5,7,...,25) were prepared and final (Jf=1,...,25) interrogated. The measurements carried out in a typical gas phase pump probe arrangement. initial vibrationally excited state was by stimulated Raman pumping using strong Q‐branch transitions. State preparation via this branch produces an isotropic spatial distribution the which is important data analysis. Narrow bandwidth lasers ensure selectivity. after monitored time‐delayed laser‐induced fluorescence A 1Au(ν3’ = 1)←X 1Σg(ν2‘ 1) transition. In general, decrease exponentially with transferred energy. constant matrix can consistently be described simple paramete...
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sci-hub.se 参考文章(55)
James T. Yardley, Introduction to Molecular Energy Transfer ,(1980)
K. P. Lawley, Dynamics of the excited state Wiley. ,(1982)
Collision theory for atoms and molecules Plenum Press. ,(1989) , 10.1007/978-1-4684-5655-4
A. S. Pine, J. P. Looney, Decoupling in the line mixing of acetylene infrared Q branches Journal of Chemical Physics. ,vol. 93, pp. 6942- 6953 ,(1990) , 10.1063/1.459471
Aa. S. Sudbo/, M. M. T. Loy, Measurement of absolute state‐to‐state rate constants for collision‐induced transitions between spin‐orbit and rotational states of NO(X 2Π, v = 2) Journal of Chemical Physics. ,vol. 76, pp. 3646- 3654 ,(1982) , 10.1063/1.443402
M. L. Koszykowski, L. A. Rahn, R. E. Palmer, M. E. Coltrin, Theoretical and experimental studies of high-resolution inverse Raman spectra of molecular nitrogen at 1-10 atm The Journal of Physical Chemistry. ,vol. 91, pp. 41- 46 ,(1987) , 10.1021/J100285A012
Michael J. Frost, Energy transfer in the 31,214151 Fermi‐resonant states of acetylene. I. Rotational energy transfer Journal of Chemical Physics. ,vol. 98, pp. 8572- 8579 ,(1993) , 10.1063/1.464517
Josef Plíva, Spectrum of acetylene in the 5-micron region Journal of Molecular Spectroscopy. ,vol. 44, pp. 145- 164 ,(1972) , 10.1016/0022-2852(72)90198-1
Sheldon Green, David L. Cochrane, Donald G. Truhlar, Accuracy of the energy‐corrected sudden (ECS) scaling procedure for rotational excitation of CO by collisions with Ar Journal of Chemical Physics. ,vol. 84, pp. 3865- 3869 ,(1986) , 10.1063/1.450097
J. D. Tobiason, A. L. Utz, F. F. Crim, State‐to‐state rotational energy transfer in highly vibrationally excited acetylene Journal of Chemical Physics. ,vol. 97, pp. 7437- 7447 ,(1992) , 10.1063/1.463515