Mechanistic Investigation of the Hydration Reaction of [Cr(η6-silabenzene)(CO)3]: Hydrido(silacyclohexadienyl)chromium Complex as an Intermediate
作者： Yusuke Tanabe , Yoshiyuki Mizuhata , Norihiro Tokitoh
DOI: 10.1246/CL.2008.720
关键词:
摘要: A key intermediate for the hydration reaction of [Cr(η6-silabenzene)(CO)3], hydrido(η5-silacyclohexadienyl)chromium complex, was successfully synthesized by silabenzene complex with...
csj.jp参考文章(19)
Keiji Wakita, Norihiro Tokitoh, Renji Okazaki, Shigeru Nagase, Synthesis and Properties of an Overcrowded Silabenzene Stable at Ambient Temperature. Angewandte Chemie. ,vol. 39, pp. 634- 636 ,(2000) , 10.1002/(SICI)1521-3757(20000204)112:3<648::AID-ANGE648>3.0.CO;2-3
Ernst Peter Kuendig, David Amurrio, Gerald Bernardinelli, Ratan Chowdhury, Agostic Complexes via Nucleophile Addition/Protonation Reactions of (η6-Benzene)tris(trifluorophosphine)chromium Organometallics. ,vol. 12, pp. 4275- 4277 ,(1993) , 10.1021/OM00035A007
Yoshiyuki Mizuhata, Takahiro Sasamori, Nobuhiro Takeda, Norihiro Tokitoh, A stable neutral stannaaromatic compound: synthesis, structure and complexation of a kinetically stabilized 2-stannanaphthalene. Journal of the American Chemical Society. ,vol. 128, pp. 1050- 1051 ,(2006) , 10.1021/JA057531D
Akihiro Shinohara, Nobuhiro Takeda, Takahiro Sasamori, Takeshi Matsumoto, Norihiro Tokitoh, Synthesis and Properties of η6-Silabenzene−M(CO)3 Complexes (M = Cr, Mo) Organometallics. ,vol. 24, pp. 6141- 6146 ,(2005) , 10.1021/OM0501778
Norio Nakata, Nobuhiro Takeda, Norihiro Tokitoh, η6-Germabenzene Complexes of Chromium and Molybdenum Angewandte Chemie International Edition. ,vol. 42, pp. 115- 117 ,(2003) , 10.1002/ANIE.200390038
M. F. Semmelhack, H. T. Hall, R. Farina, M. Yoshifuji, G. Clark, T. Bargar, K. Hirotsu, J. Clardy, .eta.5-Cyclohexadienyltricarbonylchromium(0) complexes from addition of carbon nucleophiles to .eta.6-benzenetricarbonylchromium(0). Formation, chemical and spectroscopic features, and x-ray diffraction analysis Journal of the American Chemical Society. ,vol. 101, pp. 3535- 3544 ,(1979) , 10.1021/JA00507A019
E. Peter Kündig, Allan F. Cunningham, Patrick Paglia, Dana P. Simmons, Gérald Bernardinelli, trans‐Disubstituted Cyclohexadienes via Sequential Addition of a Carbon Nucleophile and an Electrophile to (η6‐Benzene)tricarbonylchromium: Scope of Carbon Electrophiles Helvetica Chimica Acta. ,vol. 73, pp. 386- 404 ,(1990) , 10.1002/HLCA.19900730218
Takahiro Sasamori, Koji Inamura, Wataru Hoshino, Norio Nakata, Yoshiyuki Mizuhata, Yasuaki Watanabe, Yukio Furukawa, Norihiro Tokitoh, Synthesis and characterization of two isomers of 14π-electron germaaromatics: Kinetically stabilized 9-germaanthracene and 9-germaphenanthrene Organometallics. ,vol. 25, pp. 3533- 3536 ,(2006) , 10.1021/OM060371+
Norihiro Tokitoh, Norio Nakata, Akihiro Shinohara, Nobuhiro Takeda, Takahiro Sasamori, Coordination Chemistry of a Kinetically Stabilized Germabenzene: Syntheses and Properties of Stable η6‐Germabenzene Complexes Coordinated to Transition Metals Chemistry: A European Journal. ,vol. 13, pp. 1856- 1862 ,(2007) , 10.1002/CHEM.200601196
Keiji Wakita, Norihiro Tokitoh, Renji Okazaki, Nozomi Takagi, Shigeru Nagase, Crystal Structure of a Stable Silabenzene and Its Photochemical Valence Isomerization into the Corresponding Silabenzvalene Journal of the American Chemical Society. ,vol. 122, pp. 5648- 5649 ,(2000) , 10.1021/JA000309I