Preparation and electronic spectra of some alkyl- and aryl(2,2′-bipyridine)platinum(II) complexes

作者: N. Chaudhury , R.J. Puddephatt

DOI: 10.1016/S0022-328X(00)88779-3

关键词:

摘要: Abstract A series of alkyl- and aryl-(2,2′-bipyridine)-platinum (II) complexes has been prepared by displacement the diene ligand in corresponding cyclooctadiene with 2,2′-bipyridine. Dimethyl(1,10-phenanthroline)platinum(II) was an analogous way. The electronic spectra contain metal to charge transfer bands whose energy is dependent on nature substituents platinum solvent. It suggested that π-bonding important phenyl—platinum bond.

参考文章(21)
N. Chaudhury, M.G. Kekre, R.J. Puddephatt, The reactivity of methylnickel, -palladium and -platinum compounds towards alkenes and alkynes Journal of Organometallic Chemistry. ,vol. 73, ,(1974) , 10.1016/S0022-328X(00)80396-4
H. C. Clark, J. E. H. Ward, Carbon-13 nuclear magnetic resonance studies of organometallic compounds. II. trans-Phenylplatinum(II) derivatives Journal of the American Chemical Society. ,vol. 96, pp. 1741- 1748 ,(1974) , 10.1021/JA00813A016
Ichiro Hanazaki, Saburo Nagakura, Electronic structure of the tris(.alpha.,.alpha.'-dipyridyl)iron(II) ion Inorganic Chemistry. ,vol. 8, pp. 648- 654 ,(1969) , 10.1021/IC50073A047
J. N. Demas, T. F. Turner, Glenn A. Crosby, Preparation and thin-layer chromatography of cis-dicyanobis(2,2'-bipyridine)ruthenium(II) Inorganic Chemistry. ,vol. 8, pp. 674- 675 ,(1969) , 10.1021/IC50073A052
H.L. Hsieh, Reactions of naphthalene and chloro-substituted naphthalenes with lithium metal☆ Journal of Organometallic Chemistry. ,vol. 7, pp. 1- 10 ,(1967) , 10.1016/S0022-328X(00)90820-9
D. L. Webb, Laura Ancarani Rossiello, Luminescence of platinum(II) complexes Inorganic Chemistry. ,vol. 10, pp. 2213- 2218 ,(1971) , 10.1021/IC50104A025
F.J.A. des Tombe, G.J.M. van der Kerk, H.M.J.C. Creemers, N.A.D. Carey, J.G. Noltes, The synthesis and properties of some organometallic compounds containing group IV (Ge, Sn)-group II (Zn, Cd) metalmetal bonds Journal of Organometallic Chemistry. ,vol. 44, pp. 247- 252 ,(1972) , 10.1016/S0022-328X(00)82912-5