Equilibrium properties of molecular fluid mixtures

摘要: The application of perturbation theory in which all tensor interactions are taken as a the central potential to multicomponent fluid mixture nonspherical molecules arbitrary symmetry is considered. influence angle‐dependent pair arising from permanent electric multipole moments, induced dipole anisotropic dispersion and overlap forces, three‐body nonadditive classical induction interaction between asymmetric on Helmholtz free energy, some cases through third‐order theory, evaluated. applied binary mixtures consisting (i) component spherically symmetric another axially (ii) both components molecules. Comparisons with experiments made for Ar–N2, Ar–O2, Ar–CO, N2–O2 N2–CO at zero pressure isobar T=83.82 °K function composition excess G...