Effect of room temperature surface active ionic liquids on aggregated nanostructures of γ-Cyclodextrins: A picosecond fluorescence spectroscopic study

作者: Jagannath Kuchlyan , Chiranjib Banerjee , Surajit Ghosh , Niloy Kundu , Debasis Banik

DOI: 10.1016/J.CPLETT.2014.03.066

关键词:

摘要: Abstract In this Letter we report on controllable transition of aggregated γ-Cyclodextrins (γ-CDs) nanostructures by tuning the concentration a long chain ionic liquid, 1-dodecyl-3-methyl imidazolium chloride (C 12 mimCl) added to aqueous solution γ-CDs. The gradual increase in C mimCl first results breaking γ-CDs aggregates formation inclusion complexes with and then self-organizes into new supramolecular aggregate. This spontaneous from one nanostructure another has been established spectroscopic microscopic studies. It is worth mention that addition 1-octyl-3-methyl 8 does not lead any such transition.

参考文章(50)
G. González-Gaitano, P. Rodríguez, J. R. Isasi, M. Fuentes, G. Tardajos, M. Sánchez, The Aggregation of Cyclodextrins as Studied by Photon Correlation Spectroscopy Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 44, pp. 101- 105 ,(2002) , 10.1023/A:1023065823358
Kinam Park, Controlled drug delivery : challenges and strategies American Chemical Society. ,(1997)
Robin D Rogers, Kenneth R Seddon, Ionic Liquids--Solvents of the Future? Science. ,vol. 302, pp. 792- 793 ,(2003) , 10.1126/SCIENCE.1090313
Gaëlle M. Nicolle, André E. Merbach, Destruction of perfluoroalkyl surfactant aggregates by β-cyclodextrin Chemical Communications. pp. 854- 855 ,(2004) , 10.1039/B315681H
Abderrazzak Douhal, Ultrafast guest dynamics in cyclodextrin nanocavities. Chemical Reviews. ,vol. 104, pp. 1955- 1976 ,(2004) , 10.1021/CR020669J
Anjan Chakraborty, Debabrata Seth, Debdeep Chakrabarty, Nilmoni Sarkar, Photoinduced intermolecular electron transfer from dimethyl aniline to 7-amino Coumarin dyes in the surface of β-cyclodextrin Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. ,vol. 64, pp. 801- 808 ,(2006) , 10.1016/J.SAA.2005.08.007
Edward W. Castner, James F. Wishart, Spotlight on ionic liquids The Journal of Chemical Physics. ,vol. 132, pp. 120901- 120901 ,(2010) , 10.1063/1.3373178
Anthony W. Coleman, Ioannis Nicolis, Nelly Keller, Jean Pierre Dalbiez, Aggregation of cyclodextrins: an explanation of the abnormal solubility of β-cyclodextrin Journal of Inclusion Phenomena and Macrocyclic Chemistry. ,vol. 13, pp. 139- 143 ,(1992) , 10.1007/BF01053637
Rezik A. Agbaria, David Gill, Extended 2,5-diphenyloxazole-.gamma.-cyclodextrin aggregates emitting 2,5-diphenyloxazole excimer fluorescence The Journal of Physical Chemistry. ,vol. 92, pp. 1052- 1055 ,(1988) , 10.1021/J100316A012
Xueyan Zhao, Bin Dong, Liqiang Zheng, Na Li, Shaohua Zhang, Yan'an Gao, Inclusion Complexes of β-Cyclodextrin with Ionic Liquid Surfactants Journal of Physical Chemistry B. ,vol. 110, pp. 8576- 8581 ,(2006) , 10.1021/JP057478F