Isostructural 3D Ln–Ag (Ln = Eu; Dy; Ho) coordination frameworks based on mixed nicotinate and oxalate ligands: Synthesis, crystal structures and luminescence
作者： Zhi-Hui Liu , Yong-Cai Qiu , Ying-Hua Li , Guo Peng , Biao Liu
DOI: 10.1016/J.INOCHE.2008.12.011
关键词:
摘要: Abstract By control of mixed organic ligands with different geometries, three unusual 4d–4f heterometallic coordination polymers, [AgLn(nic)2(ox)] · 2H2O [Ln = Eu (1); Dy (2); Ho (3)] [nic = nicotinate; ox = oxalate] have been synthesized under hydrothermal reaction. Three structures represent 3D open frameworks that are constructed from rare zigzag lanthanide-ox-silver chains and nic linkers. Furthermore, the luminescent property complex 1 was discussed.
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