Simultaneous monitoring of temporal profiles of NO3, NO2 and O3 by incoherent broadband cavity enhanced absorption spectroscopy for atmospheric applications
作者： Tao Wu , Cécile Coeur-Tourneur , Guillaume Dhont , Andy Cassez , Eric Fertein
DOI: 10.1016/J.JQSRT.2013.08.002
关键词:
摘要: Abstract An Incoherent Broadband Cavity Enhanced Absorption Spectroscopy (IBBCEAS) setup has been developed to simultaneously monitor temporal profiles of nitrate radical (NO3), nitrogen dioxide (NO2) and ozone (O3) concentrations in the atmosphere. The IBBCEAS performance was tested an atmospheric chamber (8 m3) at room temperature (296±2) K dry conditions (RH NO3, NO2 O3 were recorded during NO2+O3 reaction compared those calculated from chemical simulations. experimental simulated data good accordance demonstrate that is effective technique in-situ real time multiple species (NO3, O3). This presents sensitivity resolution required for measurements atmosphere (both indoor outdoor) also a large potential laboratory studies simulation chamber. To our knowledge, this first instrument used follow NO2, reactions.
harvard.edu
elsevier.com
sci-hub.se 参考文章(37)
J. N. Crowley, R. Atkinson, M. E. Jenkin, M. J. Rossi, R. G. Hynes, J. Troe, R. F. Hampson, R. A. Cox, D. L. Baulch, Evaluated kinetic and photochemical data for atmospheric chemistry: Volume I - gas phase reaxtions of Ox, HOx, NOx and SOx species Atmospheric Chemical Physics. ,vol. 4, pp. 1461- 1738 ,(2004)
William P. Dubé, Steven S. Brown, Hans D. Osthoff, Maya R. Nunley, Steven J. Ciciora, Mark W. Paris, Richard J. McLaughlin, A. R. Ravishankara, Aircraft instrument for simultaneous, in situ measurement of NO3 and N2O5 via pulsed cavity ring-down spectroscopy Review of Scientific Instruments. ,vol. 77, pp. 034101- ,(2006) , 10.1063/1.2176058
Steven S. Brown, Harald Stark, Steven J. Ciciora, Richard J. McLaughlin, A. R. Ravishankara, Simultaneousin situdetection of atmospheric NO3 and N2O5 via cavity ring-down spectroscopy Review of Scientific Instruments. ,vol. 73, pp. 3291- 3301 ,(2002) , 10.1063/1.1499214
Ulrich Platt, Dieter Perner, Arthur M. Winer, Geoffrey W. Harris, James N. Pitts, Detection of NO3in the polluted troposphere by differential optical absorption Geophysical Research Letters. ,vol. 7, pp. 89- 92 ,(1980) , 10.1029/GL007I001P00089
I. Ventrillard-Courtillot, E. Sciamma O’Brien, S. Kassi, G. Méjean, D. Romanini, Incoherent broad-band cavity-enhanced absorption spectroscopy for simultaneous trace measurements of NO2 and NO3 with a LED source Applied Physics B. ,vol. 101, pp. 661- 669 ,(2010) , 10.1007/S00340-010-4253-X
A. K. Benton, J. M. Langridge, S. M. Ball, W. J. Bloss, M. Dall'Osto, E. Nemitz, R. M. Harrison, R. L. Jones, Night-time chemistry above London: measurements of NO 3 and N 2 O 5 from the BT Tower Atmospheric Chemistry and Physics. ,vol. 10, pp. 9781- 9795 ,(2010) , 10.5194/ACP-10-9781-2010
Amélie Lauraguais, Cécile Coeur-Tourneur, Andy Cassez, Abdoulaie Seydi, Rate constant and secondary organic aerosol yields for the gas-phase reaction of hydroxyl radicals with syringol (2,6-dimethoxyphenol) Atmospheric Environment. ,vol. 55, pp. 43- 48 ,(2012) , 10.1016/J.ATMOSENV.2012.02.027
K Demerjian, A review of national monitoring networks in North America Atmospheric Environment. ,vol. 34, pp. 1861- 1884 ,(2000) , 10.1016/S1352-2310(99)00452-5
Ezra C. Wood, Paul J. Wooldridge, Jens H. Freese, Tim Albrecht, Ronald C. Cohen, Prototype for in situ detection of atmospheric NO3 and N2O5 via laser-induced fluorescence. Environmental Science & Technology. ,vol. 37, pp. 5732- 5738 ,(2003) , 10.1021/ES034507W
R. Thalman, R. Volkamer, Inherent calibration of a blue LED-CE-DOAS instrument to measure iodine oxide, glyoxal, methyl glyoxal, nitrogen dioxide, water vapour and aerosol extinction in open cavity mode Atmospheric Measurement Techniques. ,vol. 3, pp. 1797- 1814 ,(2010) , 10.5194/AMT-3-1797-2010