Aqueous colloidal processing of PLZT ceramics near the morphotropic phase boundary
作者： C D Munro , K P Plucknett
DOI: 10.1179/174367509X12535211569477
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摘要: Abstract Single phase PLZT powder was fabricated using the mixed oxide approach, with a composition (6/60/40) lying on rhombohedral-tetragonal (morphotropic) boundary. Aqueous suspensions showed an IEP of pH 9·7 in absence polyelectrolyte surfactant. Inductively coupled plasma optical emission spectrometry analysis demonstrated considerable leaching Pb2+ and La3+ ions under acidic conditions. The addition ammonium salt poly(methacrylate), or PMA-NH4, decreased to pH 5-6. Suspensions were readily stabilised at basic pH low PMA-NH4 concentration (<0·1 wt-% solids). Concentrated exhibited shear thinning behaviour rates, transition thickening modest rates (i.e. 100 s−1). Excessive imposed maximum solids loading 46 vol.-% concentrated suspensions, which related somewhat ‘flake-like’ particle morphology. Slip casting resulted green sintered (1250°C for 30 min) densities ...
ingenta.com参考文章(30)
A. R. Bhatti, M. Mott, J. R. G. Evans, M. J. Edirisinghe, PZT pillars for 1-3 composites prepared by ink-jet printing Journal of Materials Science Letters. ,vol. 20, pp. 1245- 1248 ,(2001) , 10.1023/A:1010987209703
Krister Holmberg, Handbook of applied surface and colloid chemistry John Wiley. ,(2002)
Y. Waseda, A. Muramatsu, Morphology Control of Materials and Nanoparticles: Advanced Materials Processing and Characterization ,(2004)
J. Windle, B. Derby, Ink Jet Printing of PZT Aqueous Ceramic Suspensions Journal of Materials Science Letters. ,vol. 18, pp. 87- 90 ,(1999) , 10.1023/A:1006689713205
E. M. Jayasingh, C. Durgaprasad, S. C. Sharma, K. Prabhakaran, S. Raghunath, Aqueous dispersion characteristics of PMN-PT powder prepared by partial oxalate route Advances in Applied Ceramics. ,vol. 108, pp. 145- 148 ,(2013) , 10.1179/174367613X13789812363902
Masahiro KAMIYA, Ryo SASAI, Hideaki ITOH, Recovery of lead in lead zirconate titanate ceramics by wet ball mill with acidic solution Journal of the Ceramic Society of Japan. ,vol. 111, pp. 806- 810 ,(2003) , 10.2109/JCERSJ.111.806
C. Galassi, E. Roncari, C. Capiani, P. Pinasco, PZT-based suspensions for tape casting Journal of The European Ceramic Society. ,vol. 17, pp. 367- 371 ,(1997) , 10.1016/S0955-2219(96)00103-3
James E. Smay, Jennifer A. Lewis, Structural and Property Evolution of Aqueous‐Based Lead Zirconate Titanate Tape‐Cast Layers Journal of the American Ceramic Society. ,vol. 84, pp. 2495- 2500 ,(2001) , 10.1111/J.1151-2916.2001.TB01042.X
A. Navarro, J.R. Alcock, R.W. Whatmore, Aqueous colloidal processing and green sheet properties of lead zirconate titanate (PZT) ceramics made by tape casting Journal of The European Ceramic Society. ,vol. 24, pp. 1073- 1076 ,(2004) , 10.1016/S0955-2219(03)00460-6
V.A. Hackley, J. Texter, Ko Higashitani, Handbook on Ultrasonic and Dielectric Characterization Techniques for Suspended Particulates Advanced Powder Technology. ,vol. 10, pp. 443- 443 ,(1999) , 10.1163/156855299X00271