Synthesis and luminescence properties of a new polyfluorene copolymer with regulated solubility

作者: A. Charas , J. Morgado , L. Alcácer , P. Brogueira , F. Cacialli

DOI: 10.1016/J.SYNTHMET.2004.05.025

关键词:

摘要: We report on the synthesis and luminescence properties of a new random fluorene-based copolymer, BTBOX, combining 9,9-dioctylfluorene, benzothiadiazole phenylene units substituted with pendant oxetane groups, which can undergo ring-opening polymerisation. BTBOX exhibits efficient green-yellow emission. Upon UV irradiation solid films containing photoacid groups polymerise, leading to formation an insoluble crosslinked network, r-BTBOX.

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