Poly(styrenesulphonic) acid: an active and reusable acid catalyst soluble in polar solvents

作者: Manuel López Granados , Ana Carolina Alba-Rubio , Irantzu Sádaba , Rafael Mariscal , Inmaculada Mateos-Aparicio

DOI: 10.1039/C1GC15461C

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摘要: This article reports on the catalytic activity of soluble poly(styrenesulphonic) acid (PSSA) in three different reactions driven by acidic sites: tributyrin methanolysis, biodiesel synthesis and xylose dehydration to furfural. The PSSA catalyst, polar media used these reactions, displayed larger than other non-soluble sulphonic solid catalysts studied (Amberlyst 36, Amberlyst 70 Nafion®-SAC13). ultrafiltration catalyst allowed retention reutilisation for several runs. No significant decay was observed reaction repeats investigated. All results demonstrated that PSSA, a material can be obtained from polystyrene waste, is an excellent reusable conducting demanding sites.

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