An Asymptotic Expression for the Energy Levels of the Rigid Asymmetric Rotor

摘要: The energy matrix of the rigid asymmetric rotor, evaluated in terms symmetric rotor wave functions, has been examined under conditions where J is increased indefinitely. Asymptotically, assumes a form that very much like may be obtained from characteristic value problem Mathieu's differential equation. values equation serve as basis for good approximation to those levels which, given, large J, correspond small K limiting cases. differences which exist between two matrices are accounted by perturbation technique permits an accurate determination values.When lead successful estimate made functions.