Sensitization of Nd3+ by 4f-5d transition of Ce3+ in Ba2Y(BO3)2Cl phosphor for the prospective NIR applications
作者： R.A. Talewar , Sk. Mahamuda , A.S. Rao , C.P. Joshi , S.V. Moharil
DOI: 10.1016/J.JLUMIN.2018.05.035
关键词:
摘要: Abstract The Ba2Y(BO3)2Cl:Ce3+,Nd3+ phosphor was synthesized by conventional solid-state reaction method and characterized using XRD, SEM, photoluminescence (PL) excitation, PL emission decay to understand the feasibility of this for NIR emission. XRD patterns recorded Ba2Y(BO3)2Cl reveal pure crystalline monoclinic phase belong a space group P21/m. surface morphology as prepared has been investigated SEM. When excited with UV, gives broadband at 420 nm, which corresponds allowed 5d→4f transition Ce3+ ions intense emissions in range 800–1400 nm, are assigned characteristic 4F3/2→4I9/2,11/2,13/2 transitions Nd3+ ions. dependence visible emissions, lifetime energy transfer efficiency (ηETE) were detail. Excitation, spectra curves have measured prove from Nd3+. fluorescence measurements efficiencies estimated mechanisms between proposed. results indicate that sensitization is possible via 4f-5d Ce3+.
harvard.edu
sci-hub.se 参考文章(69)
P. Dorenbos, The 4fn↔4fn − 15d transitions of the trivalent lanthanides in halogenides and chalcogenides Journal of Luminescence. ,vol. 91, pp. 91- 106 ,(2000) , 10.1016/S0022-2313(00)00197-6
Jiajia Zhou, Yu Teng, Xiaofeng Liu, Zhijun Ma, Jianrong Qiu, Broadband spectral conversion of visible light to near-infrared emission via energy transfer from Ce 3+ to Nd 3+ /Yb 3+ in YAG Journal of Materials Research. ,vol. 26, pp. 689- 692 ,(2011) , 10.1557/JMR.2010.84
W.J. Schipper, G. Blasse, Luminescence in the chloroborates Ba2Ln(BO3)2Cl Journal of Alloys and Compounds. ,vol. 203, pp. 267- 269 ,(1994) , 10.1016/0925-8388(94)90745-5
John B. Gruber, Dhiraj K. Sardar, Raylon M. Yow, Toomas H. Allik, Bahram Zandi, Energy-level structure and spectral analysis of Nd3+(4f3) in polycrystalline ceramic garnet Y3Al5O12 Journal of Applied Physics. ,vol. 96, pp. 3050- 3056 ,(2004) , 10.1063/1.1776320
R.E. Avalyan, G.S. Gevorkyan, A.A. Glushko, K.B. Petrosyan, Powerful Nd:YAG laser for remote sensing Infrared Physics. ,vol. 29, pp. 213- 214 ,(1989) , 10.1016/0020-0891(89)90052-3
F Rivera-López, P Babu, Ch Basavapoornima, CK Jayasankar, V Lavín, None, Efficient Nd3+→Yb3+ energy transfer processes in high phonon energy phosphate glasses for 1.0 μm Yb3+ laser Journal of Applied Physics. ,vol. 109, pp. 123514- ,(2011) , 10.1063/1.3580475
C. Nageswara Raju, C. Adinarayana Reddy, S. Sailaja, Hyo Jin Seo, B. Sudhakar Reddy, Judd–Ofelt theory: optical absorption and NIR emission spectral studies of Nd3+:CdO–Bi2O3–B2O3 glasses for laser applications Journal of Materials Science. ,vol. 47, pp. 772- 778 ,(2012) , 10.1007/S10853-011-5853-5
Woan-Jen Yang, Liyang Luo, Teng-Ming Chen, Niann-Shia Wang, Luminescence and energy transfer of Eu- and Mn-coactivated CaAl2Si2O8 as a potential phosphor for white-light UVLED Chemistry of Materials. ,vol. 17, pp. 3883- 3888 ,(2005) , 10.1021/CM050638F
P Dorenbos, Relation between Eu2+ and Ce3+ f ↔ d-transition energies in inorganic compounds Journal of Physics: Condensed Matter. ,vol. 15, pp. 4797- 4807 ,(2003) , 10.1088/0953-8984/15/27/311
DC Yu, XY Huang, S Ye, MY Peng, QY Zhang, None, Efficient near-infrared quantum splitting in YVO4:Ho3+ for photovoltaics Solar Energy Materials and Solar Cells. ,vol. 101, pp. 303- 307 ,(2012) , 10.1016/J.SOLMAT.2012.03.001