Spectroscopy of free radicals and radical containing entrance-channel complexes in superfluid helium nanodroplets
作者： Jochen Küpper , Jeremy M. Merritt
DOI: 10.1080/01442350601087664
关键词:
摘要: The spectroscopy of free radicals and radical containing entrance-channel complexes embedded in superfluid helium nanodroplets is reviewed. collection dopants inside individual droplets represents a micro-canonical ensemble, as such each droplet may be considered an isolated cryo-reactor. unique properties the droplets, namely their low temperature (0.4 K) fast cooling rates (∼ 1016 K s−1), provide novel opportunities for formation high-resolution study molecular radicals. Radical production methods are discussed light applicability embedding droplets. spectroscopic studies performed to date on entrance / exit-channel with stable molecules detailed. observed new information potential energy surfaces several fundamental chemical reactions intermolecular interactions present open-shell systems. Prospects for...
core.ac.uk
mpg.de
harvard.edu
desy.de
sci-hub.st 参考文章(245)
E. Lee, D. Farrelly, K. B. Whaley, Rotational Level Structure ofSF6-Doped4HeNClusters Physical Review Letters. ,vol. 83, pp. 3812- 3815 ,(1999) , 10.1103/PHYSREVLETT.83.3812
K. Nauta, R. E. Miller, Rotational and vibrational dynamics of CO2 and N2O in helium nanodroplets Journal of Chemical Physics. ,vol. 115, pp. 10254- 10260 ,(2001) , 10.1063/1.1416492
Giacinto Scoles, Atomic and Molecular Beam Methods Oxford University Press. ,(1988)
Zofia. Mielke, Lester. Andrews, Matrix infrared studies of the hydrogen cyanide + ozone and hydrogen cyanide + oxygen atom systems The Journal of Physical Chemistry. ,vol. 94, pp. 3519- 3525 ,(1990) , 10.1021/J100372A030
J.M. Goodings, D.K. Bohme, Chun-Wai Ng, Detailed ion chemistry in methaneoxygen flames. II. Negative ions Combustion and Flame. ,vol. 36, pp. 45- 62 ,(1979) , 10.1016/0010-2180(79)90044-0
Michael P. Deskevich, Michael Y. Hayes, Kaito Takahashi, Rex T. Skodje, David J. Nesbitt, Multireference configuration interaction calculations for the F(P2)+HCl→HF+Cl(P2) reaction: A correlation scaled ground state (1A′2) potential energy surface The Journal of Chemical Physics. ,vol. 124, pp. 224303- 224303 ,(2006) , 10.1063/1.2192505
Anthony Stone, The Theory of Intermolecular Forces ,(2016)
Robert W. Dibble, Ulrich Maas, J. Warnatz, Combustion: Physical and Chemical Fundamentals, Modelling and Simulation, Experiments, Pollutant Formation ,(1996)
Guo-sheng Wu, George C. Schatz, G. Lendvay, De-Cai Fang, L. B. Harding, A new potential surface and quasiclassical trajectory study of H+H2O→OH+H2 Journal of Chemical Physics. ,vol. 113, pp. 3150- 3161 ,(2000) , 10.1063/1.1287329
Yaling Chen, Michael C. Heaven, Comparison of direct and resonant scattering for H2+CN(A 2Π): Collisional energy transfer versus predissociation of CN(A)–H2 complexes Journal of Chemical Physics. ,vol. 112, pp. 7416- 7424 ,(2000) , 10.1063/1.481342