Microscale Experiment on Decreases in Volume When Forming Binary Liquid Mixtures: Four Alkanol Aqueous Solutions

作者: Tetsuo Nakagawa

DOI: 10.1007/978-94-007-4860-6_29

关键词:

摘要: The volume of a liquid mixture is not equal to the sum volumes its components. In this study, microscale experiments and theoretical calculations from experimental data such as excess molar or densities are applied mixing alkanol (methanol, ethanol, 1-propanol, 2-propanol) water, observed calculated alkanol-water mixtures (aqueous solutions) obtained. Both in good agreement, alkanols water drastically reduced ca 1/25 using comparison with traditional ones. treatment also easy for high school university students. Therefore, it has been demonstrated that our methods useful informative teaching materials science first grade chemistry classes

参考文章(14)
Tetsuo Nakagawa, DETERMINATION OF PARTIAL MOLAR VOLUMES FOR BINARY SOLUTIONS VIA EXCESS MOLAR VOLUMES Journal of Science Education in Japan. ,vol. 24, pp. 179- 186 ,(2000) , 10.14935/JSSEJ.24.179
A. Carmichael, High School Chemistry Handbook ,(2010)
James L. Ealy, Lee R. Summerlin, Chemical Demonstrations: A Sourcebook for Teachers ,(1988)
Enrico Matteoli, Luciano Lepori, Solute–solute interactions in water. II. An analysis through the Kirkwood–Buff integrals for 14 organic solutes The Journal of Chemical Physics. ,vol. 80, pp. 2856- 2863 ,(1984) , 10.1063/1.447034
Otto Redlich, A. T. Kister, Algebraic Representation of Thermodynamic Properties and the Classification of Solutions Industrial & Engineering Chemistry. ,vol. 40, pp. 345- 348 ,(1948) , 10.1021/IE50458A036
Osamu Kiyohara, George C. Benson, Thermodynamics of aqueous mixtures of nonelectrolytes. I. Excess volumes of water-n-alcohol mixtures at several temperatures Journal of Solution Chemistry. ,vol. 9, pp. 791- 804 ,(1980) , 10.1007/BF00646798
Vladimir M. Petruševski, Metodija Z. Najdoski, Volume Nonadditivity of Liquid Mixtures: Modifications to Classical Demonstrations The Chemical Educator. ,vol. 6, pp. 161- 163 ,(2001) , 10.1007/S00897010478A