High atomic yield bromine-less benzylic bromination
作者： Ramon Mestres , Jes??s Palenzuela
DOI: 10.1039/B203055A
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摘要: A two-phase mixture (sodium bromide, aqueous hydrogen peroxide/carbon tetrachloride or chloroform) under visible light provides a simple and convenient system for benzylic bromination of toluenes. high atomic yield bromine atoms is attained. Substitution the chlorinated solvents by other more environmentally benign organic has been attempted good results are obtained methyl pivalate.
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