Electrochemical Grignard Reagent Synthesis for Ionic‐Liquid‐Based Magnesium–Air Batteries
作者： Daniel Luder , Yair Ein-Eli
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摘要: Metal–organic compounds are widely used in the production of fine chemicals and pharmaceutical agents. On large scales, chemical Grignard reagents (GRs) with ether solvents is difficult. The electrochemical synthesis GRs ionic-liquid-based electrolytes reported herein. presence GR product demonstrated by cyclic voltammetry 1H nuclear magnetic resonance spectroscopy comparing measured passing charge to final concentration. Additionally, high-boiling tetraethylene glycol dimethyl shown be a suitable substitute for volatile tetrahydrofuran ether, which currently used. A mechanism suggested discussed, potential importance process high-energy-density applications magnesium–air cell. Electropolishing Mg anode also observed discussed.
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