Competition between ligand centered and charge transfer lowest excited states in bis cyclometalated Rh 3+ and Ir 3+ complexes
作者： Mirco G. Colombo , Andreas Hauser , Hans U. Güdel
关键词:
摘要: … Mixing between the nn* and M LCT excited states is reflected in the … the lifetime of the excited state is mainly governed by its … have some formal ppy- --* bpy ligand-ligand charge transfer …
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Y. Ohsawa, S. Sprouse, K. A. King, M. K. DeArmond, K. W. Hanck, R. J. Watts, Electrochemistry and spectroscopy of ortho-metalated complexes of iridium(III) and rhodium(III) The Journal of Physical Chemistry. ,vol. 91, pp. 1047- 1054 ,(1987) , 10.1021/J100289A009
Yasuo Komada, Seigo Yamauchi, Noboru Hirota, Phosphorescence and zero-field optically detected magnetic resonance studies of the lowest excited triplet states of organometallic diimine complexes. 1. Rhodium bipyridine and rhodium phenanthroline complexes [Rh(bpy)3]3+ and [Rh(phen)3]3+ The Journal of Physical Chemistry. ,vol. 90, pp. 6425- 6430 ,(1986) , 10.1021/J100282A006
Mirco G. Colombo, Hans U. Guedel, Synthesis and high-resolution optical spectroscopy of bis[2-(2-thienyl)pyridinato-C3,N'](2,2'-bipyridine)iridium(III) Inorganic Chemistry. ,vol. 32, pp. 3081- 3087 ,(1993) , 10.1021/IC00066A019
B. Henderson, G. F. Imbusch, Optical spectroscopy of inorganic solids Clarendon Press , Oxford University Press. ,(1989)
Robin M. Hochstrasser, V. M. Agranovich, Spectroscopy and Excitation Dynamics of Condensed Molecular Systems ,(1983)
S. P. McGlynn, M. Kinoshita, T. Azumi, Molecular spectroscopy of the triplet state Prentice-Hall. ,(1969)
Mirco G. Colombo, Arne Zilian, Hans U. Güdel, Luminescence of Rh(III) chelate complexes: Line narrowing and the influence of host and temperature Journal of Luminescence. pp. 549- 552 ,(1991) , 10.1016/0022-2313(91)90190-7
Kazuo Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds ,(1978)
Ronald A. Krause, Synthesis of ruthenium(II) complexes of aromatic chelating heterocycles: Towards the design of luminescent compounds ChemInform. ,vol. 19, pp. 1- 52 ,(1987) , 10.1007/3-540-17881-3_1
R. J. Watts, T. P. White, B. G. Griffith, Photophysical evidence for d-d emissions from homobischelated complexes of iridium(III) Journal of the American Chemical Society. ,vol. 97, pp. 6914- 6916 ,(1975) , 10.1021/JA00856A077