1,6-Bis(4-vinylphenyl)hexane as a crosslinking agent for the preparation of crosslinked sulfonated poly(ether ether ketone) membranes by EB irradiation
作者： Sanghee Han , Mei-Shan Zhang , Junhwa Shin , Youn-Sik Lee
DOI: 10.1016/J.RADPHYSCHEM.2013.12.025
关键词:
摘要: Abstract In order to mitigate problems associated with highly sulfonated aromatic hydrocarbon membranes, such as dimensional stability, mechanical strength, and methanol crossover, poly(ether ether ketone) (SPEEK) membranes containing 1,6-bis(4-vinylphenyl)hexane (BVPH) were crosslinked by EB irradiation. Compared the pristine SPEEK membrane, exhibited significantly improved chemical strength. The crosslinking procedure slightly reduced proton conductivity of membranes. BVPH was also found reduce but permeability.
harvard.edu
elsevier.com
sci-hub.se 参考文章(23)
John Lawrence Sanchez, Synthesis and characterization of divinyl monomers for styrene-based reaction injection molding ,(2003)
Marcos A. P. Martins, Clarissa P. Frizzo, Dayse N. Moreira, Lilian Buriol, Pablo Machado, Solvent-free heterocyclic synthesis. Chemical Reviews. ,vol. 109, pp. 4140- 4182 ,(2009) , 10.1021/CR9001098
Duong Sang Phu, Chang Hyun Lee, Chi Hoon Park, So Young Lee, Young Moo Lee, Synthesis of Crosslinked Sulfonated Poly(phenylene sulfide sulfone nitrile) for Direct Methanol Fuel Cell Applications. Macromolecular Rapid Communications. ,vol. 30, pp. 64- 68 ,(2009) , 10.1002/MARC.200800496
Miaomiao Han, Gang Zhang, Ke Shao, Hongtao Li, Yang Zhang, Mingyu Li, Shuang Wang, Hui Na, Carboxyl-terminated benzimidazole-assisted cross-linked sulfonated poly(ether ether ketone)s for highly conductive PEM with low water uptake and methanol permeability Journal of Materials Chemistry. ,vol. 20, pp. 3246- 3252 ,(2010) , 10.1039/B926354C
Ju-Myung Song, Junhwa Shin, Joon-Yong Sohn, Young Chang Nho, Preparation and characterization of SPEEK membranes crosslinked by electron beam irradiation Macromolecular Research. ,vol. 19, pp. 1082- 1089 ,(2011) , 10.1007/S13233-011-1013-7
Jinhua Chen, Dengrong Li, Hiroshi Koshikawa, Masaharu Asano, Yasunari Maekawa, Crosslinking and grafting of polyetheretherketone film by radiation techniques for application in fuel cells Journal of Membrane Science. ,vol. 362, pp. 488- 494 ,(2010) , 10.1016/J.MEMSCI.2010.07.012
Chi Hoon Park, Chang Hyun Lee, Michael D. Guiver, Young Moo Lee, Sulfonated hydrocarbon membranes for medium-temperature and low-humidity proton exchange membrane fuel cells (PEMFCs) Progress in Polymer Science. ,vol. 36, pp. 1443- 1498 ,(2011) , 10.1016/J.PROGPOLYMSCI.2011.06.001
B. Smitha, S. Sridhar, A.A. Khan, Solid polymer electrolyte membranes for fuel cell applications¿a review Journal of Membrane Science. ,vol. 259, pp. 10- 26 ,(2005) , 10.1016/J.MEMSCI.2005.01.035
Miaomiao Han, Gang Zhang, Mingyu Li, Shuang Wang, Yang Zhang, Hongtao Li, Christopher M. Lew, Hui Na, Considerations of the morphology in the design of proton exchange membranes: Cross-linked sulfonated poly(ether ether ketone)s using a new carboxyl-terminated benzimidazole as the cross-linker for PEMFCs International Journal of Hydrogen Energy. ,vol. 36, pp. 2197- 2206 ,(2011) , 10.1016/J.IJHYDENE.2010.11.065
Chang Hyun Lee, Ho Bum Park, Youn Suk Chung, Young Moo Lee, Benny D. Freeman, Water Sorption, Proton Conduction, and Methanol Permeation Properties of Sulfonated Polyimide Membranes Cross-Linked with N,N-Bis(2-hydroxyethyl)-2-aminoethanesulfonic Acid (BES) Macromolecules. ,vol. 39, pp. 755- 764 ,(2006) , 10.1021/MA052226Y