Saturation effects on the hole shapes produced by photochemical hole burning: Application to the anthracene–tetracene photoadduct
作者： Mark A. Iannone , Gary W. Scott
DOI: 10.1063/1.455014
关键词:
摘要: The kinetics of photochemical spectral hole burning are modeled considering low temperature mechanisms requiring both one and two photons. calculated results compared with experimental on in the anthracene–tetracene photoadduct (AT) using single color irradiation. Better agreement is obtained for photon mechanism while assuming second absorbed by lowest triplet state AT. effects irradiation source bandwidth polarization included analysis. Photochemical transient saturation evident shapes.
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sci-hub.se 参考文章(19)
Optical Spectroscopy of Glasses Springer Netherlands. ,(1986) , 10.1007/978-94-009-4650-7
Tae-Kyu Ha, Urs P. Wild, An ab initioCI calculation of the triplet–triplet absorption spectrum of naphthalene Journal of Computational Chemistry. ,vol. 3, pp. 1- 5 ,(1982) , 10.1002/JCC.540030102
Alfred J. Meixner, Alois Renn, Stephan E. Bucher, Urs P. Wild, Spectral hole burning in glasses and polymer films: the Stark effect The Journal of Physical Chemistry. ,vol. 90, pp. 6777- 6785 ,(1986) , 10.1021/J100284A013
W. Koehler, W. Breinl, J. Friedrich, Laser photochemistry with polarized light in low-temperature glasses The Journal of Physical Chemistry. ,vol. 89, pp. 2473- 2477 ,(1985) , 10.1021/J100258A010
J. Friedrich, D. Haarer, Transient features of optical bleaching as studied by photochemical hole burning and fluorescence line narrowing Journal of Chemical Physics. ,vol. 76, pp. 61- 68 ,(1982) , 10.1063/1.442713
G. Schulte, W. Grond, D. Haarer, R. Silbey, Photochemical hole burning of phthalocyanine in polymer glasses: Thermal cycling and spectral diffusion Journal of Chemical Physics. ,vol. 88, pp. 679- 686 ,(1988) , 10.1063/1.454195
H.P.H. Thijssen, S. Völker, Pitfalls in the determination of optical homogeneous linewidths in amorphous systems by hole-burning. Influence of the structure of the host Chemical Physics Letters. ,vol. 120, pp. 496- 502 ,(1985) , 10.1016/0009-2614(85)80541-8
J. Friedrich, J. D. Swalen, D. Haarer, Electron–phonon coupling in amorphous organic host materials as investigated by photochemical hole burning Journal of Chemical Physics. ,vol. 73, pp. 705- 711 ,(1980) , 10.1063/1.440178
Sada-aki Yamamoto, Karl-Heinz Grellmann, The adiabatic photodissociation of the anthracene—tetracene photodimer Chemical Physics Letters. ,vol. 92, pp. 533- 540 ,(1982) , 10.1016/0009-2614(82)87055-3
F.W. Deeg, Larry Madison, M.D. Fayer, Transient properties of triplet bottleneck holeburning in an optically thick sample Chemical Physics. ,vol. 94, pp. 265- 271 ,(1985) , 10.1016/0301-0104(85)85082-5