Molecularly Defined Manganese Pincer Complexes for Selective Transfer Hydrogenation of Ketones
作者： Marc Perez , Saravanakumar Elangovan , Anke Spannenberg , Kathrin Junge , Matthias Beller
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摘要: For the first time an easily accessible and well-defined manganese N,N,N-pincer complex catalyzes transfer hydrogenation of a broad range ketones with good to excellent yields. This cheap earth abundant-metal based catalyst provides access useful secondary alcohols without need hydrogen gas. Preliminary investigations explore mechanism this transformation are also reported.
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