Effect of microwave calcination on catalytic properties of Pt/MgAl(Sn)Ox catalyst in cyclohexane dehydrogenation to cyclohexene
作者： Nai-liang Wang , Jian-e Qiu , Zhao-wei Wu , Jian Wu , Kui-yi You
DOI: 10.1016/J.APCATA.2015.07.009
关键词:
摘要: Abstract This paper describes an investigation on catalytic properties of Pt nanoparticles supported MgAl(Sn)Ox mixed oxide for cyclohexane dehydrogenation to cyclohexene. The supports were synthesized by microwave calcined hydrotalcite-derived precursors, and Pt/MgAl(Sn)Ox catalysts prepared incipient wetness impregnation method. characterized X-ray diffraction (XRD), hydrogen temperature-programmed reduction (H2-TPR), desorption (H2-TPD), X-Ray photoelectron spectroscopy (XPS) transmission electron microscopy (TEM). results showed that the calcination changed interfacial character between support, strengthened interaction tin facilitated high dispersion presented support. These effects resulted in higher activity, stability cyclohexene selectivity
elsevier.com
sci-hub.se 参考文章(45)
Sonia A. Bocanegra, A. Guerrero-Ruiz, Sergio R. de Miguel, Osvaldo A. Scelza, Performance of PtSn catalysts supported on MAl2O4 (M: Mg or Zn) in n-butane dehydrogenation: characterization of the metallic phase Applied Catalysis A-general. ,vol. 277, pp. 11- 22 ,(2004) , 10.1016/J.APCATA.2004.08.016
Zeeshan Nawaz, Wei Fei, Pt-Sn-Based SAPO-34 Supported Novel Catalyst for n-Butane Dehydrogenation Industrial & Engineering Chemistry Research. ,vol. 48, pp. 7442- 7447 ,(2009) , 10.1021/IE900801M
H. Feng, J.W. Elam, J.A. Libera, M.J. Pellin, P.C. Stair, Oxidative dehydrogenation of cyclohexane over alumina-supported vanadium oxide nanoliths Journal of Catalysis. ,vol. 269, pp. 421- 431 ,(2010) , 10.1016/J.JCAT.2009.11.026
G. Del Angel, A. Bonilla, Y. Peña, J. Navarrete, J.L.G. Fierro, D.R. Acosta, Effect of lanthanum on the catalytic properties of PtSn/γ-Al2O3 bimetallic catalysts prepared by successive impregnation and controlled surface reaction Journal of Catalysis. ,vol. 219, pp. 63- 73 ,(2003) , 10.1016/S0021-9517(03)00140-4
V KUZNETSOV, Mössbauer spectroscopic and chemical analysis of the composition of Sn-containing components of PtSnAl2O3(Cl) reforming catalyst Journal of Catalysis. ,vol. 99, pp. 159- 170 ,(1986) , 10.1016/0021-9517(86)90209-5
Z. Paál, A. Wootsch, D. Teschner, K. Lázár, I.E. Sajó, N. Győrffy, G. Weinberg, A. Knop-Gericke, R. Schlögl, Structural properties of an unsupported model Pt–Sn catalyst and its catalytic properties in cyclohexene transformation Applied Catalysis A-general. ,vol. 391, pp. 377- 385 ,(2011) , 10.1016/J.APCATA.2010.05.047
Ricardo Morales, Luis Melo, Aura Llanos, Francisco Zaera, Characterization of bifunctional PtSn/H[Al]ZSM5 catalysts: a comparison between two impregnation strategies Journal of Molecular Catalysis A-chemical. ,vol. 228, pp. 227- 232 ,(2005) , 10.1016/J.MOLCATA.2004.09.036
S. H. Overbury, P. A. Bertrand, G. A. Somorjai, THE SURFACE COMPOSITION OF BINARY SYSTEMS. PREDICTION OF SURFACE PHASE DIAGRAMS OF SOLID SOLUTIONS Chemical Reviews. ,vol. 75, pp. 547- 560 ,(1975) , 10.1021/CR60297A001
Sung-Cheng Hu, Yu-Wen Chen, Partial Hydrogenation of Benzene to Cyclohexene on Ruthenium Catalysts Supported on La2O3−ZnO Binary Oxides Industrial & Engineering Chemistry Research. ,vol. 36, pp. 5153- 5159 ,(1997) , 10.1021/IE970300Y
Charles Kappenstein, Maurice Gue´rin, Károly Lázár, Károly Matusek, Zoltán Paál, Characterisation and activity in n-hexane rearrangement reactions of metallic phases on Pt-Sn/Al2O3 catalysts of different preparations Journal of the Chemical Society, Faraday Transactions. ,vol. 94, pp. 2463- 2473 ,(1998) , 10.1039/A803014F