Equation of state for chain molecules: Continuous‐space analog of Flory theory
作者： Ronald Dickman , Carol K. Hall
DOI: 10.1063/1.450881
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摘要: New, accurate equations of state for fluids chain molecules are derived as generalizations the well‐known Flory and Flory–Huggins lattice theories to continuous space. Comparison with results new Monte Carlo simulations athermal chains (freely jointed hard disks spheres), extending over a wide range densities, reveals that generalized equation provides an prediction pressure.
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