Cobalt-catalyzed cross-dehydrogenative coupling of imidazo[1,2-a]pyridines with isochroman using molecular oxygen as the oxidant

作者: Qingjing Yang , Sifeng Li , Jun (Joelle) Wang

DOI: 10.1039/C7QO00875A

关键词:

摘要: A cobalt-catalyzed cross-dehydrogenative coupling of 2-arylimidazo[1,2-a]pyridines with isochroman using molecular oxygen as the oxidant is reported. broad range reacted smoothly to afford corresponding products in moderate good yields. The advantages this method are: inexpensive catalysts, environmentally benign conditions and operational convenience.

参考文章(76)
Tongtong Wang, Michael Schrempp, Andreas Berndhäuser, Olav Schiemann, Dirk Menche, Efficient and General Aerobic Oxidative Cross-Coupling of THIQs with Organozinc Reagents Catalyzed by CuCl2: Proof of a Radical Intermediate. Organic Letters. ,vol. 17, pp. 3982- 3985 ,(2015) , 10.1021/ACS.ORGLETT.5B01845
Likun Jin, Jie Feng, Guoping Lu, Chun Cai, Di‐tert‐butyl Peroxide (DTBP)‐Mediated Oxidative Cross‐ Coupling of Isochroman and Indole Derivatives Advanced Synthesis & Catalysis. ,vol. 357, pp. 2105- 2110 ,(2015) , 10.1002/ADSC.201500048
Qingjing Yang, Pui Ying Choy, Wai Chung Fu, Baomin Fan, Fuk Yee Kwong, Copper-Catalyzed Oxidative C-H Amination of Tetrahydrofuran with Indole/Carbazole Derivatives. Journal of Organic Chemistry. ,vol. 80, pp. 11193- 11199 ,(2015) , 10.1021/ACS.JOC.5B01990
Esther Boess, Devarajulu Sureshkumar, Abhishek Sud, Cornelia Wirtz, Christophe Farès, Martin Klussmann, Mechanistic Studies on a Cu-Catalyzed Aerobic Oxidative Coupling Reaction with N-Phenyl Tetrahydroisoquinoline: Structure of Intermediates and the Role of Methanol As a Solvent Journal of the American Chemical Society. ,vol. 133, pp. 8106- 8109 ,(2011) , 10.1021/JA201610C
Chandra M. R. Volla, Iuliana Atodiresei, Magnus Rueping, Catalytic C-C bond-forming multi-component cascade or domino reactions: pushing the boundaries of complexity in asymmetric organocatalysis. Chemical Reviews. ,vol. 114, pp. 2390- 2431 ,(2014) , 10.1021/CR400215U
Margarita Brovetto, Daniela Gamenara, Patricia Saenz Méndez, Gustavo A. Seoane, C−C Bond-Forming Lyases in Organic Synthesis Chemical Reviews. ,vol. 111, pp. 4346- 4403 ,(2011) , 10.1021/CR100299P
Audrey Gallud, Ophélie Vaillant, Ludovic T. Maillard, Dominique P. Arama, Joëlle Dubois, Marie Maynadier, Vincent Lisowski, Marcel Garcia, Jean Martinez, Nicolas Masurier, Imidazopyridine-fused [1,3]-diazepinones: synthesis and antiproliferative activity. European Journal of Medicinal Chemistry. ,vol. 75, pp. 382- 390 ,(2014) , 10.1016/J.EJMECH.2014.01.044
Michael Ghobrial, Michael Schnürch, Marko D. Mihovilovic, Direct Functionalization of (Un)protected Tetrahydroisoquinoline and Isochroman under Iron and Copper Catalysis: Two Metals, Two Mechanisms Journal of Organic Chemistry. ,vol. 76, pp. 8781- 8793 ,(2011) , 10.1021/JO201511D
Yinuo Wu, Jun Wang, Fei Mao, Fuk Yee Kwong, Palladium-Catalyzed Cross-Dehydrogenative Functionalization of C(sp2)H Bonds Chemistry - An Asian Journal. ,vol. 9, pp. 26- 47 ,(2014) , 10.1002/ASIA.201300990