X-ray crystal structure of a ternary copper(II) vitamin B6 complex, hydroxo(2,2′-bipyridyl)(pyridoxinato) copper(II) monohydrate. A rare example of monodentate coordination of copper(II) by the hydroxyl ion
作者： Irimpan I. Mathews , S.P.Sudhakara Rao , M. Nethaji
DOI: 10.1016/S0277-5387(00)83372-0
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摘要: Abstract A ternary metal complex involving Vitamin B6 with the formula [Cu(bipy)(pn) (OH)]H2O (bipy = 2,2′-bipyridine, pn anionic pyridoxine) has been synthesized and studied in solid state by means of spectroscopy X-ray crystallography. The geometry around copper(II) is distorted square pyramidal, two oxygens from phenolic 4-(hydroxymethyl) groups pn, nitrogens bipy an axial OH− ion forming coordination sphere. In this structure exists a new form deprotonation group. also provides rare example monodentate hydroxyl to copper.
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