Alkylation of isobutane with butenes over solid superacids, SO42−/ZrO2 and SO42−/TiO2

作者: Canxiong Guo , Sheng Yao , Jianhua Cao , Zaihu Qian

DOI: 10.1016/0926-860X(94)85157-3

关键词:

摘要: Solid superacids SO 4 2− /ZrO 2 and SO 4 2− /TiO 2 were applied in the alkylation of isobutane with butenes at a reaction temperature of 100 C. They showed high activity, selectivity …

参考文章(7)
W GARWOOD, Paraffin-olefin alkylation over a crystalline aluminosilicate Journal of Catalysis. ,vol. 11, pp. 175- 177 ,(1968) , 10.1016/0021-9517(68)90025-0
Tuo Jin, Tsutomu Yamaguchi, Kozo Tanabe, Mechanism of acidity generation on sulfur-promoted metal oxides The Journal of Physical Chemistry. ,vol. 90, pp. 4794- 4796 ,(1986) , 10.1021/J100411A017
Makoto Hino, Sakari Kobayashi, Kazushi Arata, Solid catalyst treated with anion. 2. Reactions of butane and isobutane catalyzed by zirconium oxide treated with sulfate ion. Solid superacid catalyst Journal of the American Chemical Society. ,vol. 101, pp. 6439- 6441 ,(1979) , 10.1021/JA00515A051
Tsutomu Yamaguchi, Tuo Jin, Kozo Tanabe, Structure of acid sites on sulfur-promoted iron oxide The Journal of Physical Chemistry. ,vol. 90, pp. 3148- 3152 ,(1986) , 10.1021/J100405A022
Tuo Jin, Motoi Machida, Tsutomu Yamaguchi, Kozo Tanabe, Infrared study of sulfur-containing iron oxide. Behavior of sulfur during reduction and oxidation Inorganic Chemistry. ,vol. 23, pp. 4396- 4398 ,(1984) , 10.1021/IC00193A063
Y.F. Chu, A.W. Chester, Reactions of isobutane with butene over zeolite catalysts Zeolites. ,vol. 6, pp. 195- 200 ,(1986) , 10.1016/0144-2449(86)90047-3
Kozi HATAKEYAMA, Teruo SUZURA, Mamoru YAMANE, Alkylation of Isobutane with Butene over Solid Superacid (SO42-/ZrO2) Catalyst Journal of The Japan Petroleum Institute. ,vol. 34, pp. 267- 272 ,(1991) , 10.1627/JPI1958.34.267