Luminescence properties of the Eu-doped porous glass and spontaneous reduction of Eu3+ to Eu2+
作者： Qiang Zhang , Yanbo Qiao , Bin Qian , Guoping Dong , Jian Ruan
DOI: 10.1016/J.JLUMIN.2009.07.013
关键词:
摘要: Abstract The luminescent properties of Eu 3+ -doped porous glass were investigated and reduction to 2+ was observed when the glasses heat treated in air. absorption, emission excitation spectra measured results significantly depended on treating temperature. integral intensity ions at different temperatures also investigate this process. Electron spin resonance (ESR) samples measured, which confirmed effect. A possible mechanism discussed explain
core.ac.uk
harvard.edu
elsevier.com
sci-hub.se 参考文章(19)
M. A. Zaitoun, D. M. Goken, L. S. Bailey, T. Kim, C. T. Lin, Thermoanalysis and Emission Properties of Eu3+/Eu2+ in Eu3+-Doped Xerogels Journal of Physical Chemistry B. ,vol. 104, pp. 189- 196 ,(2000) , 10.1021/JP991873M
Yan Cong, Bin Li, Bingfu Lei, Xiaojun Wang, Chunxu Liu, Junye Liu, Wenlian Li, Enhancement of luminescence intensity and increase of emission lifetime in Eu3+ -doped 3CdO-Al2O3-3SiO2 amorphous system Journal of Luminescence. ,vol. 128, pp. 105- 109 ,(2008) , 10.1016/J.JLUMIN.2007.05.016
Masakazu Anpo, Norikazu Aikawa, Yutaka Kubokawa, Michel Che, Catherine Louis, Elio Giamello, Photoluminescence and photocatalytic activity of highly dispersed titanium oxide anchored onto porous Vycor glass The Journal of Physical Chemistry. ,vol. 89, pp. 5017- 5021 ,(1985) , 10.1021/J100269A025
Jinan Xia, Danping Chen, Jianrong Qiu, Congshan Zhu, Rare-earth-doped silica microchip laser fabricated by sintering nanoporous glass Optics Letters. ,vol. 30, pp. 47- 49 ,(2005) , 10.1364/OL.30.000047
Yasuko Yamada Maruo, Jiro Nakamura, Masahiro Uchiyama, Masanori Higuchi, Katsuyuki Izumi, Development of formaldehyde sensing element using porous glass impregnated with Schiff's reagent Sensors and Actuators B-chemical. ,vol. 129, pp. 544- 550 ,(2008) , 10.1016/J.SNB.2007.09.002
E. Fritsch, L. Mihut, M. Baibarac, I. Baltog, M. Ostrooumov, S. Lefrant, J. Wery, Luminescence of oxidized porous silicon: Surface-induced emissions from disordered silica micro- to nanotextures Journal of Applied Physics. ,vol. 90, pp. 4777- 4782 ,(2001) , 10.1063/1.1410887
M. Dejneka, E. Snitzer, R.E. Riman, Blue, green and red fluorescence and energy transfer of Eu3+ in fluoride glasses Journal of Luminescence. ,vol. 65, pp. 227- 245 ,(1995) , 10.1016/0022-2313(95)00073-9
Jing He, Xiaofen Li, D.G Evans, Xue Duan, Chengyue Li, A new support for the immobilization of penicillin acylase Journal of Molecular Catalysis B: Enzymatic. ,vol. 11, pp. 45- 53 ,(2000) , 10.1016/S1381-1177(00)00218-6
Zhiwu Pei, Qinghua Zeng, Qiang Su, The application and a substitution defect model for Eu3+→Eu2+ reduction in non-reducing atmospheres in borates containing BO4 anion groups Journal of Physics and Chemistry of Solids. ,vol. 61, pp. 9- 12 ,(2000) , 10.1016/S0022-3697(99)00237-1
Sabine Chabrillat, Hermann J. Kaufmann, Joachim Hill, Andreas A. Mueller, Bruno Merz, Helmut Echtler, Research opportunities for studying land degradation with spectroscopic techniques Remote Sensing for Environmental Monitoring, GIS Applications, and Geology II. ,vol. 4886, pp. 11- 19 ,(2003) , 10.1117/12.462362