Review: The chirality and bionic studies of polyoxometalates: the synthetic strategy and structural chemistry
作者： Wei-Lin Chen , Hua-Qiao Tan , En-Bo Wang
DOI: 10.1080/00958972.2011.645812
关键词:
摘要: Chiral polyoxometalates (POMs) have been a hot topic because of their potential applications in the fields stereoselective catalysis, bio-simulation, sensing, nonlinear materials, and medicine. In view extensive work on chiral POMs, four parts are included this review to give broad overview recent developments POMs: first, synthetic strategy molecular design POMs; second, research progress POMs including structure chemistry, resolution, theoretical calculations; third, bionic involving studies helix structures molecules. The final part shows outlook catalysis biomedical studies, which ultimate goals investigations.
sci-hub.se 参考文章(76)
Haiyan An, Zhengbo Han, Tieqi Xu, Changgong Meng, Enbo Wang, Self-assembly of polyoxometalate clusters and metal–organic coordination fragments into 1D homochiral chains Inorganic Chemistry Communications. ,vol. 11, pp. 914- 917 ,(2008) , 10.1016/J.INOCHE.2008.04.040
Brigitte Nohra, Hani El Moll, L. Marleny Rodriguez Albelo, Pierre Mialane, Jérôme Marrot, Caroline Mellot-Draznieks, Michael O’Keeffe, Rosa Ngo Biboum, Joël Lemaire, Bineta Keita, Louis Nadjo, Anne Dolbecq, Polyoxometalate-based metal organic frameworks (POMOFs): structural trends, energetics, and high electrocatalytic efficiency for hydrogen evolution reaction Journal of the American Chemical Society. ,vol. 133, pp. 13363- 13374 ,(2011) , 10.1021/JA201165C
Miyao Inoue, Toshihiro Yamase, Synthesis and Crystal Structures of γ-Type Octamolybdates Coordinated by Chiral Lysines Bulletin of the Chemical Society of Japan. ,vol. 68, pp. 3055- 3063 ,(1995) , 10.1246/BCSJ.68.3055
J. L. T. Waugh, D. P. Shoemaker, L. Pauling, On the structure of the heteropoly anion in ammonium 9-molybdomanganate, (NH4)6MnMo9O32.82O Acta Crystallographica. ,vol. 7, pp. 438- 441 ,(1954) , 10.1107/S0365110X54001302
Achim Müller, Frank Peters, Michael T. Pope, Dante Gatteschi, Polyoxometalates: Very Large Clusters-Nanoscale Magnets. Chemical Reviews. ,vol. 98, pp. 239- 272 ,(1998) , 10.1021/CR9603946
Likai Yan, Xavier López, Jorge J. Carbó, Richard Sniatynsky, Dean C. Duncan, Josep M. Poblet, On the origin of alternating bond distortions and the emergence of chirality in polyoxometalate anions. Journal of the American Chemical Society. ,vol. 130, pp. 8223- 8233 ,(2008) , 10.1021/JA711008N
Taohai Li, Feng Li, Jian Lü, Zhengang Guo, Shuiying Gao, Rong Cao, Pentadecatungstate with dinuclear cerium(III) unit: synthesis, crystal structure and properties. Inorganic Chemistry. ,vol. 47, pp. 5612- 5615 ,(2008) , 10.1021/IC700726D
Zhi-Ming Zhang, Shuang Yao, Yang-Guang Li, Rodolphe Clérac, Ying Lu, Zhong-Min Su, En-Bo Wang, Protein-Sized Chiral Fe168 Cages with NbO-Type Topology Journal of the American Chemical Society. ,vol. 131, pp. 14600- 14601 ,(2009) , 10.1021/JA903776H
Lin Xu, Chao Qin, Xinlong Wang, Yongge Wei, Enbo Wang, Hydrothermal synthesis and structure of a new helical chain constructed from only molybdenum-oxide building blocks. Inorganic Chemistry. ,vol. 42, pp. 7342- 7344 ,(2003) , 10.1021/IC034331Z
Maxim N. Sokolov, Natalya V. Izarova, Eugenia V. Peresypkina, Dmitry A. Mainichev, Vladimir P. Fedin, Zirconium and hafnium aqua complexes [(H2O)3M(P2W17O61)]6−: Synthesis, characterization and substitution of water by chiral ligand Inorganica Chimica Acta. ,vol. 362, pp. 3756- 3762 ,(2009) , 10.1016/J.ICA.2009.04.038