Isotopes as tracers of sources of lead and strontium in aerosols (TSP & PM2.5) in Beijing
作者： David Widory , Xiande Liu , Shuping Dong
DOI: 10.1016/J.ATMOSENV.2010.06.036
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摘要: Abstract Even after its being phased out in gasoline the late 90s, lead (Pb) is still present at relatively high levels atmosphere of Beijing, China (0.10–0.18 μg m −3 ). Its origin subject to debate as several distinct sources may contribute observed pollution levels. This study proposes constrain origin(s) Pb and strontium (Sr) aerosols, by coupling both Sr isotope systematics. The characterisation main (road traffic, smelters, metal refining plants, coal combustion, cement factories, soil erosion) shows that they can unambiguously be discriminated multi-isotope approach ( 206 Pb/ 204 87 Sr/ 86 Sr). total suspended particulates (TSP) fine particles (PM 2.5 ) from Beijing vicinity indicates size fractions are controlled same sources. Lead isotopes indicate plants major source atmospheric lead, followed thermal power stations other combustion processes. role this latter confirmed of strontium isotopes. Occasionally, emissions and/or input alteration isotopically detectable.
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David Widory, Lead isotopes decipher multiple origins within single PM10 samples in the atmosphere of Paris Isotopes in Environmental and Health Studies. ,vol. 42, pp. 97- 105 ,(2006) , 10.1080/10256010500502736
William M White, Francis Albarède, Philippe Télouk, High-precision analysis of Pb isotope ratios by multi-collector ICP-MS Chemical Geology. ,vol. 167, pp. 257- 270 ,(2000) , 10.1016/S0009-2541(99)00182-5
Andreas D. Kappos, Peter Bruckmann, Thomas Eikmann, Norbert Englert, Uwe Heinrich, Peter Höppe, Eckehard Koch, Georg H.M. Krause, Wolfgang G. Kreyling, Knut Rauchfuss, Peter Rombout, Verena Schulz-Klemp, Wolf R. Thiel, H.-Erich Wichmann, Health effects of particles in ambient air. International Journal of Hygiene and Environmental Health. ,vol. 207, pp. 399- 407 ,(2004) , 10.1078/1438-4639-00306
Yoriko Yokoo, Takanori Nakano, Masataka Nishikawa, Hao Quan, Mineralogical variation of Sr–Nd isotopic and elemental compositions in loess and desert sand from the central Loess Plateau in China as a provenance tracer of wet and dry deposition in the northwestern Pacific Chemical Geology. ,vol. 204, pp. 45- 62 ,(2004) , 10.1016/J.CHEMGEO.2003.11.004
M.R. Palmer, J.M. Edmond, The strontium isotope budget of the modern ocean Earth and Planetary Science Letters. ,vol. 92, pp. 11- 26 ,(1989) , 10.1016/0012-821X(89)90017-4
Christian Pin, Chantal Bassin, Evaluation of a strontium-specific extraction chromatographic method for isotopic analysis in geological materials Analytica Chimica Acta. ,vol. 269, pp. 249- 255 ,(1992) , 10.1016/0003-2670(92)85409-Y
C. Block, R. Dams, Lead contents of coal, coal ash and fly ash Water Air and Soil Pollution. ,vol. 5, pp. 207- 211 ,(1975) , 10.1007/BF00282962
Jerome O. Nriagu, The rise and fall of leaded gasoline Science of The Total Environment. ,vol. 92, pp. 13- 28 ,(1990) , 10.1016/0048-9697(90)90318-O
B Hamelin, F Grousset, E.R Sholkovitz, Pb isotopes in surficial pelagic sediments from the North Atlantic Geochimica et Cosmochimica Acta. ,vol. 54, pp. 37- 47 ,(1990) , 10.1016/0016-7037(90)90193-O
W.T. Sturges, L.A. Barrie, Stable lead isotope ratios in arctic aerosols: evidence for the origin of arctic air pollution Atmospheric Environment. ,vol. 23, pp. 2513- 2519 ,(1989) , 10.1016/0004-6981(89)90263-1