Determination of the structure of ArHCl
作者： Stewart E. Novick , Paul Davies , Stephen J. Harris , William Klemperer
DOI: 10.1063/1.1680332
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摘要: The radio frequency and microwave spectra of K = 0 states ArHCl ArDCl have been measured by molecular beam electric resonance spectroscopy. rotational hyperfine structure constants for the lowest vibrational state four isotopic species are ArH35 ClArD35 ClB (B+C)/2 1.678511 (5)GHzB − 2DJ 1.657596 (10)GHzDJ=20.33 (20)kHz(eqQ)aC1 −36.250 (20)MHz(eqQ)a=−23.027(10)MHz(eqQ)aD +102.3 (50)kHzμa=0.81144(10)Dμa=1.00355(70)D ArH37 ClArD37 ClB 1.631566 1.611876 (10)GHz Only has observed. molecule is extremely nonrigid. average Ar–Cl distance 4.006 A in 4.025 ArDCl. Ar–Cl–H angle acute amplitude zero point bending large. near 45°, while Ar–Cl–D 34°. Ar–HCl bond stretching computed to be 32.2 cm−1 from observed centrifugal distortion constant.
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sci-hub.se 参考文章(16)
F. Albert Cotton, Advanced Inorganic Chemistry ,(1999)
A. M. Leonardi‐Cattolica, K. O. Prins, J. S. Waugh, Proton Spin–Lattice Relaxation in HCl–Ar Mixtures The Journal of Chemical Physics. ,vol. 54, pp. 769- 774 ,(1971) , 10.1063/1.1674910
H. Friedmann, S. Kimel, THEORY OF SHIFTS OF VIBRATION-ROTATION LINES OF DIATOMIC MOLECULES IN NOBLE GAS MATRICES. INTERMOLECULAR FORCES IN CRYSTALS. Journal of Chemical Physics. ,vol. 43, pp. 3925- 3939 ,(1965) , 10.1063/1.1696622
E. W. Kaiser, Dipole Moment and Hyperfine Parameters of H35Cl and D35Cl The Journal of Chemical Physics. ,vol. 53, pp. 1686- 1703 ,(1970) , 10.1063/1.1674245
W. G. Von Holle, D. W. Robinson, Far‐Infrared Spectra of HCl in Solid Ar and Kr The Journal of Chemical Physics. ,vol. 53, pp. 3768- 3770 ,(1970) , 10.1063/1.1674573
H A Gebbie, N W B Stone, Measurement of Widths and Shifts of Pure Rotation Lines of Hydrogen Chloride Perturbed by Rare Gases Proceedings of the Physical Society. ,vol. 82, pp. 309- 314 ,(1963) , 10.1088/0370-1328/82/2/317
J. M. Parson, P. E. Siska, Y. T. Lee, Intermolecular Potentials from Crossed‐Beam Differential Elastic Scattering Measurements. IV. Ar+Ar The Journal of Chemical Physics. ,vol. 56, pp. 1511- 1516 ,(1972) , 10.1063/1.1677399
Walter B. Neilsen, Roy G. Gordon, On a semiclassical study of molecular collisions. II. Application to HCl‐argon The Journal of Chemical Physics. ,vol. 58, pp. 4149- 4170 ,(1973) , 10.1063/1.1678972
S. Bratož, M. L. Martin, Infrared Spectra of Highly Compressed Gas Mixtures of the Type HCl+X. A Theoretical Study The Journal of Chemical Physics. ,vol. 42, pp. 1051- 1062 ,(1965) , 10.1063/1.1696042
R. G. Gordon, Relations Between Vibrational Spectroscopy and the Isotope Effect on Vapor Pressures Journal of Chemical Physics. ,vol. 44, pp. 576- 581 ,(1966) , 10.1063/1.1726728