NMR Study of (Sr;Ba;La) 2 Fe 1+y Mo 1¡y O 6 Double Perovskites

作者: D. Zając , Cz. Kapusta , P.C. Riedi , M. Sikora , C.J. Oates

DOI: 10.12693/APHYSPOLA.106.759

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摘要: The 95 Mo and 97 NMR spin-echo study of (Sr,Ba,La)2Fe1+yMo1iyO6 double perovskites is reported. Powder samples Ba1:44Sr0:36La0:2FeMoO6 (Ba0:8Sr0:2)2i2xLax#xFe1+yMo1iyO6, where # denotes vacancies, for: x = 0; y 0:1; 0:2 0:3; 0 were measured at 4.2 K no applied magnetic fleld. signals are observed 55{100 MHz for the main line 30{55 low-frequency satellite. satellite attributed to ideal defect positions atoms. La vacancy doping introduce more defects, however, increasing Fe/Mo ratio decreases amount sites. causes a pattern high frequency side spectrum, which related difierent numbers next neighbours. efiect an increase in electron density corresponding moment adjacent sites reveals local character doping.

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